51559-01-4Relevant articles and documents
Highly regioselective rearrangement of 2,3-diaryl-oxiranes into 2,2-diarylacetaldehydes catalyzed by ytterbium porphyrin complex, Yb(TPP)OTf
Takanami, Toshikatsu,Nakajima, Shin-ichiro,Nakadai, Shoichi,Hino, Fumio,Suda, Kohji
experimental part, p. 365 - 374 (2009/09/06)
[5,10,15,20-Tetraphenylporphynato]ytterbium(III) triflate, Yb(TPP)-OTf, is an efficient Lewis acid catalyst for the highly regioselective rearrangement of 2,3-diaryloxiranes into 2,2-diarylacetaldehydes. The catalytic process can be easily performed not only in dichloroethane but also in a more environmentally friendly solvent, benzotrifluoride.
Synthesis and structure-activity relationship studies of novel 2-diarylethyl substituted (2-carboxycycloprop-1-yl)glycines as high-affinity group II metabotropic glutamate receptor ligands.
Sorensen, Ulrik S,Bleisch, Thomas J,Kingston, Anne E,Wright, Rebecca A,Johnson, Bryan G,Schoepp, Darryle D,Ornstein, Paul L
, p. 197 - 205 (2007/10/03)
The major excitatory neurotransmitter in the central nervous system, (S)-glutamic acid , activates both ionotropic and metabotropic excitatory amino acid receptors. Its importance in connection to neurological and psychiatric disorders has directed great