51583-69-8Relevant articles and documents
Crown-ether styryl dyes 15. Synthesis and two pathways of regio- and stereospecific cation-dependent -autophotocycloaddition of chromogenic 15-crown-5-ether betaines of quinoline series
Gromov, S. P.,Fedorova, O. A.,Ushakov, E. N.,Buevich, A. V.,Alfimov, M. V.
, p. 2131 - 2136 (1995)
Styryl dyes (4a,b) containing a 15-crown-5 fragment and isomeric 2- and 4-quinolinium residues with an N-sulfopropyl substituent undergo -autophotocycloaddition to give cyclobutane derivatives (9a,b) in acetonitrile only in the presence of Mg(ClO4)2 or Ca(ClO4)2.The stereospecificity of both pathways of photocycloaddition and its efficiency are explained by the preorganization of the supramolecular dimers derived from the trans-isomers of the dyes when they are bound into complexes with Mg and Ca cations. - Keywords: crown ether styryl dyes; complex formation; -photocycloaddition; cyclobutane derivatives; 1H NMR spectra.
Microwave assisted sulfopropylation of N-heterocycles using 1,3-propane sultone
Adamczyk, Maciej,Rege, Sushil
, p. 9587 - 9588 (2007/10/03)
Dramatic rate acceleration was observed for N-sulfopropylation of heterocyclic compounds (1a-h) using 1,3-propane sultone(2) under microwave irradiation affording the N-sulfopropylated compounds (3a-h) in 68-95% yield.