5159-20-6

Basic information

• Product Name: 1-methyl-2-tosyl-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole
• Synonyms: 1-methyl-2-tosyl-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole
• CAS NO: 5159-20-6
• Molecular Weight: 340.446
• Mol File: 5159-20-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-methyl-2-tosyl-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl-2-tosyl-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole(5159-20-6)
• EPA Substance Registry System: 1-methyl-2-tosyl-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole(5159-20-6)

Safety Data

• Hazardous Substances Data: 5159-20-6(Hazardous Substances Data)

Upstream product

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• 2506-10-7 eleagnine 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 486-84-0 harmane 

Relevant articles and documents

Dehydrogenation of N-Heterocycles by Superoxide Ion Generated through Single-Electron Transfer

Nitrogen-containing heteroarene motifs are found in numerous pharmaceuticals, natural products, and synthetic materials. Although several elegant methods for synthesis of these compounds through dehydrogenation of the corresponding saturated heterocycles have been reported, some of the methods are hampered by long reaction times, harsh conditions, and the need for catalysts that are not readily available. This work reports a novel method for dehydrogenation of N-heterocycles. Specifically, O2.? generated in situ acts as the oxidant for N-heterocycle substrates that are susceptible to oxidation through a hydrogen atom transfer mechanism. This method provides a general, green route to N-heteroarenes.