51759-07-0

Basic information

• Product Name: Acetic acid, [(4-methoxyphenyl)methoxy]-, methyl ester
• CAS NO: 51759-07-0
• Molecular Formula: C11H14O4
• Molecular Weight: 210.23
• Mol File: 51759-07-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Acetic acid, [(4-methoxyphenyl)methoxy]-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, [(4-methoxyphenyl)methoxy]-, methyl ester(51759-07-0)
• EPA Substance Registry System: Acetic acid, [(4-methoxyphenyl)methoxy]-, methyl ester(51759-07-0)

Safety Data

• Hazardous Substances Data: 51759-07-0(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 88920-24-5 p-methoxybenzyloxy acetic acid 
• 105-13-5 4-Methoxybenzyl alcohol 
• 96-32-2 bromoacetic acid methyl ester 

Downstream Products

• 781671-85-0 (+)-[(S)R]-3-(p-methoxybenzyloxy)-1-(p-tolylsulfinyl)-2-propanone 
• 1241850-02-1 C₁₈H₁₈O₅ 
• 1241850-50-9 methyl (2S,3R)-3-hydroxy-2-[(4-methoxybenzyl)oxy]-3-phenylpropanoate 
• 1255204-00-2 p-methoxybenzyl 2,2-dideutero-2-hydroxyethyl ether 
• 1198184-86-9 [3-(4-methoxy-benzyloxy)-2-oxo-propyl]-phosphonic acid dimethyl ester 
• 37115-41-6 8-chloro-6-(2-chloro-phenyl)-1-(4-methoxy-benzyloxymethyl)-4H-benzo[f][1,2,4]triazolo[4,3-a][1,4]diazepine 
• 177798-94-6 tert-Butyl-[(S)-1-[((4E,6E,8E)-dodeca-4,6,8-trienyl)oxymethyl]-2-(4-methoxy-benzyloxy)-ethoxy]-diphenyl-silane 
• 177798-90-2 tert-Butyl-[(R)-1-(4-methoxy-benzyloxymethyl)-2-((S)-toluene-4-sulfinyl)-ethoxy]-diphenyl-silane 
• 177798-87-7 (S)-2-(tert-Butyl-diphenyl-silanyloxy)-3-(4-methoxy-benzyloxy)-propan-1-ol 
• 177798-89-9 (R)-1-(4-Methoxy-benzyloxy)-3-((S)-toluene-4-sulfinyl)-propan-2-ol 
• 203387-32-0 methyl (4R,7S,8S,11S,14E,16Z,20S)-20-(tert-butyl(diphenyl)silyloxy)-4,8-dimethyl-3,9-dioxo-2,7,11-tri-(p-methoxybenzyloxy)-unicosa-14,16-dienoate 
• 78132-73-7 4-(4-methoxybenzyloxy)butanoic acid methyl ester 
• 121289-23-4 p-methoxybenzyloxyacetaldehyde 
• 848486-81-7 4-(4-methoxybenzyloxy)[1-13C]but-2-enoic acid methyl ester 

Relevant articles and documents

Synthesis of 13C-labeled γ-hydroxybutyrates for EPR studies with 4-hydroxybutyryl-CoA dehydratase

4-Hydroxybutyryl-CoA dehydratase from Clostridium aminobutyricum catalyses the reversible dehydration of its substrate 4-hydroxybutyryl-CoA (4-HB-CoA) to crotonyl CoA. The enzyme contains one [4Fe-4S]2+ cluster and one flavin adenine dinucleotide (FAD) molecule per homotetramer. Incubation of the enzyme with its substrate under equilibrium conditions followed by freezing at 77 K induced the EPR-spectrum of a neutral flavin semiquinone (g = 2.005, linewidth 2.1 mT), while at 10 K additional signals were detected. In an attempt to characterize these signals, 4-HB-CoA molecules specifically labeled with 13C have been synthesized. This was achieved via 13C- labeled γ-butyrolactones, which were obtained from 13C-labeled bromoacetic acids by efficient synthetic routes. Incubation of the 13C-labeled 4-hydroxybutyrate-CoA molecules with 4-hydroxybutyryl-CoA dehydratase did not lead to marked broadening of the signals.