5176-20-5Relevant articles and documents
Solvolysis of syn- and anti-N-Chloro-1,4-dihydro-1,4-iminonaphthalenes
Durrant, Michael L.,Malpass, John R.
, p. 1028 - 1030 (1981)
The configuration of chlorine determines the course of methanolysis of the title compounds; new structures are assigned to the reaction products and the rates of reaction of the anti-N-chloroamines are shown to vary according to the ability of the substituents in the benzo-ring to encourage benzo-participation.
Azabicycloalkenes as synthetic intermediates - Synthesis of azabicyclo[x.3.0]alkane scaffolds
Buchert, Marina,Meinke, Sebastian,Prenzel, Alexander H. G. P.,Deppermann, Nina,Maison, Wolfgang
, p. 5553 - 5556 (2006)
A general method to synthesize functionalized azabicyclo[X.3.0]alkane scaffolds 5 is reported. Key intermediates are azabicycloalkenes such as 1 and 2, which are acylated with unsaturated carboxylic acids and subsequently submitted to tandem olefin metathesis. The resulting bicyclic heterocycles are versatile intermediates for different dipeptide mimetics and can be used as intermediates for natural products with indolizidine scaffolds or analogues thereof.
Preparation and Spectroscopic Studies of the 1,4-Dihydro-1,4-iminonaphthalene (7-Azabenzonorbornadiene) Ring System
Davies, John W.,Durrant, Michael L.,Walker, Matthew P.,Belkacemi, Djaballah,Malpass, John R.
, p. 861 - 884 (2007/10/02)
The synthesis of a range of N-alkyl 1,4-dihydro-1,4-iminonaphthalenes (7-azabenzonorbornadienes) and reduced derivatives is described together with 1,4-dihydro-1,4- and 9,10-dihydro-9,10- iminoanthracenes.VT NMR studies lead to unambiguous assignment of i
