51767-61-4Relevant articles and documents
Silver-Promoted Direct Phosphorylation of Bulky C(sp2)-H Bond to Build Fully Substituted β-Phosphonodehydroamino Acids
Cao, Hao-Qiang,Liu, Hao-Nan,Liu, Zhe-Yuan,Qiao, Baokun,Zhang, Fa-Guang,Ma, Jun-An
supporting information, p. 6414 - 6419 (2020/09/02)
A general and practical cross-dehydrogenative coupling protocol between readily available trisubstituted α,β-dehydro α-amino carboxylic esters and H-phosphites is described. This C(sp2)-H phosphorylation reaction proceeds with absolute Z-selectivity promoted by silver salt in a radical relay manner. The bulky tetrasubstituted β-phosphonodehydroamino acids were obtained in grams and added new modules to the toolkit for peptide modifications.
Cycloaddition of 4,5-dihydrooxazol-5-one derivatives to 4-methylbenzene-1,2-dithiol
Tikdari,Fozooni,Vazee,Hamidian
, p. 1046 - 1049 (2007/10/03)
Reactions of 4,5-dihydrooxazol-5-one derivatives with 4-methylbenzene-1,2- dithiol in the presence of triethylamine includes nucleophilic attack by the thiol group on the carbonyl carbon atom in the oxazole ring, followed by opening of the latter and recy