51786-43-7

Basic information

• Product Name: N-(2,5-dimethylphenyl)-N-methylnitrous amide
• Synonyms: N-(2,5-dimethylphenyl)-N-methylnitrous amide
• CAS NO: 51786-43-7
• Molecular Weight: 164.207
• Mol File: 51786-43-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(2,5-dimethylphenyl)-N-methylnitrous amide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2,5-dimethylphenyl)-N-methylnitrous amide(51786-43-7)
• EPA Substance Registry System: N-(2,5-dimethylphenyl)-N-methylnitrous amide(51786-43-7)

Safety Data

• Hazardous Substances Data: 51786-43-7(Hazardous Substances Data)

Upstream product

• 21354-48-3 2,5-dimethyl-N-methylaniline 
• 10113-40-3 N-(2,5-dimethylphenyl)formamide 
• 17485-25-5 3-methyl-N-nitroso-N-methylaniline 

Relevant articles and documents

Rh(III)-catalyzed C-H alkylation of arenes using alkylboron reagents

Rhodium(III)-catalyzed direct alkylation of arenes using commercially available alkyltrifluoroborates is disclosed. Oximes, heteroarenes, azomethines, N-nitrosoamines, and amides are viable directing groups to entail this transformation. The alkyl group in the boron reagent can be extended to primary alkyls, benzyl, and cycloalkyls, and the reaction proceeded with controllable mono- and dialkylation selectivity when both ortho C-H sites are accessible.