51942-32-6

Basic information

• Product Name: N-[2-(methylsulfanyl)phenyl]benzamide
• CAS NO: 51942-32-6
• Molecular Formula: C₁₄H₁₃NOS
• Molecular Weight: 243.3241
• Mol File: 51942-32-6.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 301.1°C at 760 mmHg
• Flash Point: 135.9°C
• Density: 1.2g/cm³
• Vapor Pressure: 0.00108mmHg at 25°C
• Refractive Index: 1.638
• CAS DataBase Reference: N-[2-(methylsulfanyl)phenyl]benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-[2-(methylsulfanyl)phenyl]benzamide(51942-32-6)
• EPA Substance Registry System: N-[2-(methylsulfanyl)phenyl]benzamide(51942-32-6)

Safety Data

• Hazardous Substances Data: 51942-32-6(Hazardous Substances Data)

Upstream product

• 2987-53-3 2-(Methylthio)aniline 
• 98-88-4 benzoyl chloride 
• 87012-08-6 N-benzoyl-N-<2-(methylthio)phenyl>propen-2-ylamine 
• 137-07-5 2-amino-benzenethiol 
• 87012-20-2 (RS)-3-methyl-3,4-dihydro-2H-[1,4]benzothiazine 
• 87011-99-2 4-benzoyl-3-methyl-2,3-dihydro-1,4-benzothiazine 
• 3058-47-7 methyl 2-nitrophenyl sulfide 
• 624-92-0 Dimethyldisulphide 
• 4231-62-3 1-benzoyl-1H-benzotriazole 
• 2179-60-4 methyl n-propyl disulfide 
• 65-85-0 benzoic acid 

Downstream Products

• 883-93-2 2-Phenylbenzothiazole 
• 73153-48-7 2-benzoylaminophenyl methyl sulphone 
• 93681-56-2 N-Ethyl-N-(2-methylsulfanyl-phenyl)-benzamide 
• 65936-07-4 2-benzamidophenyl methyl sulphoxide 
• 93681-67-5 4-Ethyl-3-phenyl-4H-benzo[1,4]thiazine 
• 93681-69-7 4-Ethyl-3-phenyl-4H-benzo[1,4]thiazine 1-oxide 
• 93681-59-5 2-(N-ethylbenzamido)phenyl methyl sulphoxide 
• 93681-71-1 4-Ethyl-3-phenyl-4H-benzo[1,4]thiazine 1,1-dioxide 
• 93681-61-9 2-(N-ethylbenzamido)phenyl methyl sulphone 
• 93681-64-2 2-ethylaminophenyl phenacyl sulphone 
• 107611-14-3 4,6-dibromo-2-phenyl-benzothiazole 
• 447413-03-8 C₁₄H₁₃NO₂S 

Relevant articles and documents

Exogenous Photosensitizer-, Metal-, and Base-Free Visible-Light-Promoted C-H Thiolation via Reverse Hydrogen Atom Transfer

Visible-light-driven, intramolecular C(sp2)-H thiolation has been achieved without addition of a photosensitizer, metal catalyst, or base. This reaction induces the cyclization of thiobenzanilides to benzothiazoles. The substrate absorbs visible light, and its excited state undergoes a reverse hydrogen-atom transfer (RHAT) with 2,2,6,6-tetramethylpiperidine N-oxyl to form a sulfur radical. The addition of the sulfur radical to the benzene ring gives an aryl radical, which then rearomatizes to benzothiazole via RHAT.

Diverse Visible-Light-Promoted Functionalizations of Benzotriazoles Inspired by Mechanism-Based Luminescence Screening

Three new visible-light-promoted functionalizations of benzotriazole substrates were discovered using a mechanism-based screening method. ortho-Thiolated, borylated, and alkylated N-arylbenzamide products were obtained under mild reaction conditions in a new denitrogenative synthetic approach to functionalized aniline derivatives. The functional group tolerance of the borylation reaction was further analyzed in the first application of an additive-based robustness screen in a photocatalytic transformation. All the functionalizations proceed via photocatalytically initiated chain mechanisms as indicated by determination of the reaction quantum yields and Stern–Volmer analyses.

Eliminative Ring Fission of 4-Acyl-2,3-dihydro-4H-1,4-benzothiazines

The behavior of 4-acyl-2,3-dihydro-1,4-benzothiazines 1-11 upon treatment with lithium diisopropylamide (LDA) in THF at -78 deg C has been examined.Very marked differences have been observed.Whereas unsubstituted and monosubstituted derivatives (1-4) read