51956-75-3

Basic information

• Product Name: N-(diethoxyphosphoryl)toluene-p-sulphonamide
• Synonyms: N-(diethoxyphosphoryl)toluene-p-sulphonamide
• CAS NO: 51956-75-3
• Molecular Weight: 307.307
• Mol File: 51956-75-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: N-(diethoxyphosphoryl)toluene-p-sulphonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(diethoxyphosphoryl)toluene-p-sulphonamide(51956-75-3)
• EPA Substance Registry System: N-(diethoxyphosphoryl)toluene-p-sulphonamide(51956-75-3)

Safety Data

• Hazardous Substances Data: 51956-75-3(Hazardous Substances Data)

Upstream product

• 15548-15-9 N-4-methylphenylsufonyl phosphoramidic dichloride 
• 141-52-6 sodium ethanolate 
• 1068-21-9 Diethyl phosphoramidate 
• 98-59-9 p-toluenesulfonyl chloride 
• 127-65-1 chloroamine-T 
• 762-04-9 phosphonic acid diethyl ester 
• 70-55-3 toluene-4-sulfonamide 
• 814-49-3 diethyl chlorophosphate 
• 18522-92-4 sodium p-toluenesulfonamide 
• 3576-26-9 N-4-methylphenylsufonyl phosphazene trichloride 

Downstream Products

• 1428365-09-6 C₂₂H₃₄N₂O₁₀P₂PdS₂ 
• 1387601-42-4 C₂₂H₂₁NO₂S 
• 936012-00-9 (2S,4R)-2-phenyl-4-propyl-N-tosylazetidine 
• 936011-98-2 (2R,4S)-2-benzyl-4-ethyl-1-tosylazetidine 

Relevant articles and documents

Organophosphorus ligands with XPNSO skeleton (X = O, S) and their Pd(II) complexes. Crystal and molecular structure of [{XP(OEt)2}(O 2SR)]NH (X = O, R = Me, Ph; X = S, R = C6H 4Cl-4) and Pd[{SP(OEt)2}(O2SC6H 4Cl-4)N]2

Several organophosphorus acids of type [{XP(OEt)2}(O 2SR)]NH [X = O, R = Me (1), Ph (2), C6H4CH 3-4 (3); X = S, R = C6H4Cl-4 (4)] were obtained by a method based on the reaction between (EtO)2P(X)NHLi and the corresponding organosulfonyl chloride. They were subsequently deprotonated with KOBut. Salt metathesis reactions between PdCl2 and the corresponding potassium salts K[{XP(OEt)2}(O2SR)N] [X = O, R = Me (5), Ph (6), C6H4CH3-4 (7); X = S, R = C6H4Cl-4 (8)] in a 1:2 molar ratio resulted in palladium(II) complexes of type Pd[{XP(OEt)2}(O2SR)N] 2 [X = O, R = Me (9), Ph (10), C6H4CH 3-4 (11); X = S, R = C6H4Cl-4 (12)]. In a similar way was obtained the palladium(II) complex Pd[(SPPh2)(O 2SPh)N]2 (13), using the appropriate reagents. All compounds were characterized by multinuclear NMR (1H, 13C, 31P) and infrared spectroscopy. The potassium salts and the palladium complexes were investigated also by mass spectrometry. Single-crystal X-ray diffraction studies revealed a layered supramolecular assembly in case of acid 1, a monomeric structure for compound 4, while in case of compound 2 dimeric associations are formed in the solid state by NH?OP hydrogen bonding. A trans-S,N-coordination pattern of the organophosphorus ligand was found in the palladium complex 12. Moreover, short Cl?H contacts result in a polymeric [Pd[{SP(OEt)2}(O2SC6H 4Cl-4)N]2]n chain.

REACTION OF N-SODIO-N-CHLOROARENESULFONAMIDES WITH DIALKYL PHOSPHITES

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