520-63-8Relevant articles and documents
Expedient pyrrolizidine synthesis by propargylsilane addition to N-acyliminium ions followed by gold-catalyzed α-allenyl amide cyclization
Breman, Arjen C.,Dijkink, Jan,Van Maarseveen, Jan H.,Kinderman, Sape S.,Hiemstra, Henk
supporting information; experimental part, p. 6327 - 6330 (2009/12/24)
(Chemical Equation Presented) A reaction sequence, involving the addition of (substituted) propargylsilanes to lactam-derived N-acyliminium ions followed by gold-catalyzed cyclization of the resulting α-allenyl amide, is applied in expedient syntheses of
Isoechinatine, a pyrrolizidine alkaloid from Cynoglossum furcatum
Ravikumar,Lakshmanan
, p. 406 - 409 (2007/10/03)
The pyrrolizidine alkaloids of Cynoglossum furcatum have been isolated and characterized. They are isoechinatine 1, a new pyrrolizidine ester alkaloid, echinatine, neocoramandaline and a free necine heliotridine. Isoechinatine is formulated as 9-(O)-(+)-viridiflorylheliotridine. 3-Hydroxy 6-methylpyridine has also been isolated and characterized.
Intramolecular Allylstannane Cyclizations in Alkaloid Synthesis: Applications to Pyrrolizidine Alkaloids
Keck, Gary E.,Cressman, Erik N. K.,Enholm, Eric J.
, p. 4345 - 4349 (2007/10/02)
Syntheses of (+/-)-isoretronecanol, (+/-)-supinidine, (-)-dihydroxyheliotridane, and (+)-heliotridine are detailed.The key step in each case involves an intramolecular acyliminium ion cyclization onto a suitably positioned allylstannane for construction o