52197-14-5Relevant articles and documents
The symmetrical porphyrazine with annulated six membered rings
Onay, Hilal,Esat, Burak,?ztürk, Ramazan
, p. 1314 - 1316 (2010)
Tetrakis(cyclohexylpyrazino)porphyrazinato magnesium(II) with annulated six membered rings has been prepared by two different methods. In Method A: cyclotetramerization of 2,3-dicyano-5,6-cyclohexanopyrazine (1) in the presence of Mg(OPr)2 in n-propanol afforded the tetrakis(cyclohexylpyrazino)porphyrazinato magnesium(II) (2). In Method B: selenodiazole rings on the periphery of tetrakis(selenodiazole)porphyrazinato magnesium(II) were opened by the action of H2S to yield the vicinal diamino functionalities. The ring closure of the vicinal diamino groups with 1,2-cyclohexanedione afforded the tetrakis(cyclohexylpyrazino) porphyrazinato magnesium(II) (2).
Direct and catalytic synthesis of quinoxaline derivatives from epoxides and ene-1,2-diamines
Antoniotti, Sylvain,Du?ach, Elisabet
, p. 3971 - 3973 (2007/10/03)
We describe here a new synthesis of quinoxaline derivatives by a Bi-catalyzed oxidative coupling of epoxides and ene-1,2-diamines.