52250-06-3

Basic information

• Product Name: 2-(6-Benzyloxy-benzo[1,3]dioxol-5-yl)-1-(2-benzyloxy-4-methoxy-phenyl)-3,3-dimethoxy-propan-1-one
• CAS NO: 52250-06-3
• Molecular Weight: 556.612
• Mol File: 52250-06-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(6-Benzyloxy-benzo[1,3]dioxol-5-yl)-1-(2-benzyloxy-4-methoxy-phenyl)-3,3-dimethoxy-propan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(6-Benzyloxy-benzo[1,3]dioxol-5-yl)-1-(2-benzyloxy-4-methoxy-phenyl)-3,3-dimethoxy-propan-1-one(52250-06-3)
• EPA Substance Registry System: 2-(6-Benzyloxy-benzo[1,3]dioxol-5-yl)-1-(2-benzyloxy-4-methoxy-phenyl)-3,3-dimethoxy-propan-1-one(52250-06-3)

Safety Data

• Hazardous Substances Data: 52250-06-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 52249-89-5 (E)-3-(6-Benzyloxy-benzo[1,3]dioxol-5-yl)-1-(2-benzyloxy-4-methoxy-phenyl)-propenone 

Relevant articles and documents

Oxidative rearrangement of pentaalkoxychalcones with phenyl-iodine(III) bis(trifluoroacetate) (PIFA): Synthesis of (±)-10-bromopterocarpin and (±)-pterocarpin

The oxidative rearrangement of pentaalkoxychalcones using the hypervalent iodine compound, phenyliodine(III) bis(trifluoroacetate) (PIFA), has been examined. Treatment of 2,2′-bis(benzyloxy)-4′-methoxy-4,5-methylenedioxychalcone with PIFA gives a rearrangement product in low yield, but 2,2′-bis(benzyloxy)-3-bromo-4′-methoxy-4,5-methylenedioxychalcone yields the rearrangement product, which leads to (±)-bromopterocarpin and (±)-pterocarpin.