52486-23-4 Usage
Description
(1alpha,3alpha,4alpha,6alpha)-4,7,7-trimethylbicyclo[4.1.0]heptan-3-ol, also known as bornyl alcohol, is a bicyclic organic compound belonging to the terpene family. It is naturally found in the essential oils of various plants, such as pine, fir, and camphor, and is characterized by its strong pine-like scent.
Uses
Used in Perfumery:
(1alpha,3alpha,4alpha,6alpha)-4,7,7-trimethylbicyclo[4.1.0]heptan-3-ol is used as a fragrance ingredient in perfumes due to its strong pine-like scent.
Used in Aromatherapy:
(1alpha,3alpha,4alpha,6alpha)-4,7,7-trimethylbicyclo[4.1.0]heptan-3-ol is used in aromatherapy for its potential calming and refreshing effects.
Used in Traditional Medicine:
(1alpha,3alpha,4alpha,6alpha)-4,7,7-trimethylbicyclo[4.1.0]heptan-3-ol has been used in traditional medicine for its potential anti-inflammatory, antiviral, and antibacterial properties.
Used in Flavor and Fragrance Production:
(1alpha,3alpha,4alpha,6alpha)-4,7,7-trimethylbicyclo[4.1.0]heptan-3-ol is used in the production of flavorings and fragrances due to its distinctive scent.
Used in Organic Synthesis:
(1alpha,3alpha,4alpha,6alpha)-4,7,7-trimethylbicyclo[4.1.0]heptan-3-ol is used as a starting material in the synthesis of other organic compounds.
Check Digit Verification of cas no
The CAS Registry Mumber 52486-23-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,2,4,8 and 6 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 52486-23:
(7*5)+(6*2)+(5*4)+(4*8)+(3*6)+(2*2)+(1*3)=124
124 % 10 = 4
So 52486-23-4 is a valid CAS Registry Number.
52486-23-4Relevant articles and documents
Regioselective Routes to Nucleophilic Optically Active 2- and 3-Carene Systems
Paquette, Leo A.,Ross, Robert J.,Shi, Yao-Jun
, p. 1589 - 1598 (2007/10/02)
Commercially available (+)-3-carene (4) is shown to be capable of efficient conversion to vinyl bromides 28, 46, and 49 and to vinyl stannane 44.All four compounds stem from (+)-3-norcaranone (23), an optically pure ketone best prepared by epoxidation of 4, followed by oxirane ring opening, acetylation, ozonolysis, and CrCl2-promoted reduction.The strong proclivity exhibited by 23 to enolize in the cyclopropyl carbinyl sense is used to advantage to gain entry to 28 and 44.Remarkably, the tosylhydrazone of (+)-3-norcaranone (45) is distinguished from its ketoneprogenitor 23 by its capacity for highly regioselective deprotonation from the alternative α-position.The crossover has made possible synthetic access to 46 and 49.Other chemistry of this class of compounds is also presented, inluding a route to 51, a vinyl bromide epimeric to 49.Especially relevant to future work in the ingenol area is the ability of these molecules to serve as nucleophiles.Several reactions involving 28 are provided as exemplary of this property.
Novel Method for Hydroboration of Olefins Using Electrolysis
Shundo, Ryushi,Matsubara, Yoshiharu,Nishiguchi, Ikuzo,Hirashima, Tsuneaki
, p. 2033 - 2036 (2007/10/02)
A first example of electrochemical hydroboration of olefins was found.Anodic oxidation of sodium borohydride in the presence of olefins in diglyme followed by conventional oxidation gave the corresponding alcohols regio- and stereoselectively in good yields.
