52516-77-5

Basic information

• Product Name: Benzene, 1,1'-[(1Z)-1-chloro-1-butene-1,4-diyl]bis-
• CAS NO: 52516-77-5
• Molecular Formula: C16H15Cl
• Molecular Weight: 242.748
• Mol File: 52516-77-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-[(1Z)-1-chloro-1-butene-1,4-diyl]bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-[(1Z)-1-chloro-1-butene-1,4-diyl]bis-(52516-77-5)
• EPA Substance Registry System: Benzene, 1,1'-[(1Z)-1-chloro-1-butene-1,4-diyl]bis-(52516-77-5)

Safety Data

• Hazardous Substances Data: 52516-77-5(Hazardous Substances Data)

Upstream product

• 100-47-0 benzonitrile 
• 637-59-2 1-Bromo-3-phenylpropane 
• 104-53-0 3-phenyl-propionaldehyde 
• 98-07-7 Benzotrichlorid 
• 5407-91-0 1,4-diphenylbutan-1-one 

Downstream Products

• 14533-17-6 (1Z,3E)-1-chloro-1,4-diphenylbuta-1,3-diene 
• 55373-69-8 (Z,Z)-1,4-dichloro-1,4-diphenyl-1,3-butadiene 
• 52516-76-4 (Z)(Z)-1-Brom-4-chlor-1,4-diphenylbuta-1,3-dien 

Relevant articles and documents

Stereoselective CrCl2-mediated condensation of aldehydes with functionalized 1,1,1-trichlorides: Synthesis of trisubstituted (Z)-chloroolefins

The CrCl2-mediated condensation of aldehydes 1 with a variety of functionalized 1,1,1-trichlorides 2 affords trisubstituted chloroolefins 4 in excellent yields and generally high Z-stereoselectivity. The intermediate dichlorohydrin adducts 3 can be isolated in good yields under conditions of limited reagent and reduced temperature.