52554-66-2

Basic information

• Product Name: PtI₂{Sb(C₆H₅)3}2
• CAS NO: 52554-66-2
• Molecular Weight: 1155.02
• Mol File: 52554-66-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: PtI₂{Sb(C₆H₅)3}2(CAS DataBase Reference)
• NIST Chemistry Reference: PtI₂{Sb(C₆H₅)3}2(52554-66-2)
• EPA Substance Registry System: PtI₂{Sb(C₆H₅)3}2(52554-66-2)

Safety Data

• Hazardous Substances Data: 52554-66-2(Hazardous Substances Data)

Upstream product

• 10025-99-7 potassium tetrachloroplatinate(II) 
• 603-36-1 triphenylantimony 
• 7681-82-5 sodium iodide 
• 1148055-74-6 Pt(triphenylstibine)2Cl2 
• 12266-70-5 C₈H₈PtI₂ 

Relevant articles and documents

Trans influence of triphenylstibine. Crystal and molecular structures of cis-[PtCl2 (SbPh3)2] and trans-[PtI2 (SbPh3)2]

Crystals of cis-[PtCl2(SbPh3)2] (1) are monoclinic, space group P21/a with a=20.5708(12), b=10.1942(4), c=33.3984(15) A, β=94.394(4)° and Z= 8. Substitution of chloride for iodide yields trans-[Ptl2(SbPh3)2] (2), the crystals of which are monoclinic, space group P21/c with a=18.108(4), b=10.102(2), c=19.115(5) A, β=95.241(16)° and Z=4. The average Pt-Cl distance in 1 is 2.338(12) A, implying a trans influence of triphenyl stibine comparable with that of triphenyl phosphine, as opposed to what has been reported earlier. IR and Raman data for 1 and 2 are reported and discussed.

Inorganic linkage isomerism of the thiocyanate ion

Linkage isomers of metal complexes of the type M-SCN (thiocyanato) and M-NCS (isothiocyanato) are reported for the compounds [Pd(As(C6H5)3)2X2] and [Pd(bipy)X2]. The method of preparation d