52567-56-3

Basic information

• Product Name: (-)-α-Cyclogeranylethanol
• Synonyms: (-)-α-Cyclogeranylethanol
• CAS NO: 52567-56-3
• Molecular Weight: 182.306
• Mol File: 52567-56-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (-)-α-Cyclogeranylethanol(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-α-Cyclogeranylethanol(52567-56-3)
• EPA Substance Registry System: (-)-α-Cyclogeranylethanol(52567-56-3)

Safety Data

• Hazardous Substances Data: 52567-56-3(Hazardous Substances Data)

Upstream product

• 52612-54-1 (+)-(R)-3-(2,6,6-Trimethyl-2-cyclohexen-1-yl)-(E)-propensaeure 
• 52567-54-1 (E)-3-((R)-2,6,6-Trimethyl-cyclohex-2-enyl)-acrylic acid methyl ester 
• 24190-29-2 (R)-α-ionone 
• 725739-83-3 phosphoric acid diethyl ester (R)-2-iodo-4,4-dimethylcyclohex-2-enyl ester 
• 725739-97-9 (R)-3-(2-iodo-6,6-dimethylcyclohex-2-enyl)propionic acid ethyl ester 
• 341497-26-5 (R)-4,4-dimethyl-2-iodo-2-cyclohexen-1-ol 
• 157952-85-7 2-iodo-4,4-dimethyl-cyclohex-2-enone 
• 1073-13-8 4,4-dimethylcyclohexenone 
• 52567-55-2 3-((R)-2,6,6-Trimethyl-cyclohex-2-enyl)-propionic acid methyl ester 

Downstream Products

• 52612-55-2 (1R,2R)-2-(3-Hydroxy-propyl)-1,3,3-trimethyl-cyclohexanol 
• 52567-59-6 3-((S)-2,2-Dimethyl-6-methylene-cyclohexyl)-propan-1-ol 
• 52567-60-9 3-((R)-2,2-Dimethyl-6-methylene-cyclohexyl)-propan-1-ol 
• 147379-73-5 (3)-<(R)-2,6,6-trimethl-2-cyclohexenyl>propanal 
• 24190-29-2 (R)-α-ionone 
• 472-78-6 α-ionol 
• 83059-15-8 (2E)-3-[(1R)-2,6,6-trimethyl-2-cyclohexen-1-yl]acrylaldehyde 

Relevant articles and documents

Enantioselective synthesis of α-ionone derivatives using an anti SN2′ substitution of functionalized zinc organometallics

(Equation Presented) The allylic substitution of sterically hindered (2-iodocycloalkyl)phosphates proceeds with complete anti SN2′ stereoselectivity with mixed diorganozincs of the type RZnCH 2SiMe3 in the presence of CuCN·2LiCI. Only the group R of the copper-zinc reagent is transferred in the allylic substitution. This method was used to prepare odoriferous substances such as (R)-α-ionone in 97% ee and (R)-dihydro-α-ionone in 98% ee.