52601-77-1

Basic information

• Product Name: 4,10-bis[(4-methylphenyl)sulfonyl]-1,7-dioxa-4,10-diazacyclododecane
• Synonyms: 4,10-bis[(4-methylphenyl)sulfonyl]-1,7-dioxa-4,10-diazacyclododecane
• CAS NO: 52601-77-1
• Molecular Formula: C₂₂H₃₀N₂O₆S₂
• Molecular Weight: 482.6134
• Mol File: 52601-77-1.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4,10-bis[(4-methylphenyl)sulfonyl]-1,7-dioxa-4,10-diazacyclododecane(CAS DataBase Reference)
• NIST Chemistry Reference: 4,10-bis[(4-methylphenyl)sulfonyl]-1,7-dioxa-4,10-diazacyclododecane(52601-77-1)
• EPA Substance Registry System: 4,10-bis[(4-methylphenyl)sulfonyl]-1,7-dioxa-4,10-diazacyclododecane(52601-77-1)

Safety Data

• Hazardous Substances Data: 52601-77-1(Hazardous Substances Data)

Upstream product

• 59945-34-5 N,N'-Bis(p-tolylsulfonyl)-1,5-diamino-3-oxapentane 
• 7460-82-4 diethylene glycol ditosylate 
• 5414-19-7 1,1'-oxybis(2-bromo-ethane) 
• 118187-55-6 N,N-bis<2-<2-<(p-tolylsulfonyl)oxy>ethoxy>ethyl>-p-toluenesulfonamide 
• 70-55-3 toluene-4-sulfonamide 
• 111-44-4 3-oxa-1,5-dichloropentane 
• 98-59-9 p-toluenesulfonyl chloride 
• 72358-83-9 N,N-bis<2-(2-hydroxyethoxy)ethyl>-4-methylbenzenesulfonamide 

Downstream Products

• 294-92-8 diaza[12]crown-4 
• 118074-98-9 4,10-bis<2-(p-tolylsulphonylamino)ethyl>-1,7-dioxa-4,10-diazacyclododecane 
• 118074-99-0 4,10-bis(p-tolylsulphonyl)-7,16,21-trioxa-1,4,10,13-tetra-azabicyclo<11.5.5>tricosane 
• 118075-00-6 4,13-bis(p-tolylsulphonyl)-7,10,19,24-tetraoxa-1,4,13,16-tetra-azabicyclo<14.5.5>hexacosane 
• 121057-92-9 4,11-bis(p-tolylsulphonyl)-6,9-etheno-17,22-dioxa-1,4,11,14-tetra-azabicyclo<12.5.5>tetracosa-6,8-diene 
• 121031-84-3 4,9-bis(p-tolylsulphonyl)benz-15,20-dioxa-1,4,9,12-tetra-azabicyclo<10.5.5>docosane 
• 60598-02-9 4,7-bis(p-tolylsulphonyl)-13,18-dioxa-1,4,7,10-tetra-azabicyclo<8,5,5>icosane 

Relevant articles and documents

A new design strategy for molecular recognition in heterogeneous systems: A universal crystal-face growth inhibitor for barium sulfate [26]

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An Alternative Synthesis of Cyclic Aza Compounds

A series of cyclic mono-, di- and poly-aza compounds has been synthesised in moderate to good yields by reaction of p-toluenesulfonamide and either α,ω-ditosylates or α,ω-dichlorides.

MACROHETEROCYCLES. PART 44. FACILE SYNTHESIS OF AZACROWN ETHERS AND CRYPTANDS IN A TWO-PHASE SYSTEM

A facile procedure is proposed for the preparation of azacrown ethers and cryptands by condensation of dibromides or ethylene glycol bis(toluene-p-sulphonate)s with acyclic bis(sulphonamide)s or with bisdiazacrown ethers, respectively.The reaction was carried out in a two-phase system of aqueous alkali-toluene (benzene)in the presence of quaternary ammonium salts as phase transfer catalysts.The catalytic activity decreased in the sequence: Bu4NI ca.Bu4NBr > Bu4NCl > Bu4NHSO4 > Et3NCH2C6H5NCl.Maximum yields of twelve-membered azacrown ethers are obtained when lithium hydroxide is used, while crown ethers of larger size are observed in the presence of sodium or potassium hydroxides; this may be due to a template effect.