52629-45-5

Basic information

• Product Name: Benzeneacetyl chloride, 4-(1,1-dimethylethyl)-
• CAS NO: 52629-45-5
• Molecular Formula: C12H15ClO
• Molecular Weight: 210.704
• Mol File: 52629-45-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzeneacetyl chloride, 4-(1,1-dimethylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetyl chloride, 4-(1,1-dimethylethyl)-(52629-45-5)
• EPA Substance Registry System: Benzeneacetyl chloride, 4-(1,1-dimethylethyl)-(52629-45-5)

Safety Data

• Hazardous Substances Data: 52629-45-5(Hazardous Substances Data)

Upstream product

• 943-27-1 4'-t-butylacetophenone 
• 253185-03-4 tert-butylbenzene 

Downstream Products

• 78983-43-4 Acetic acid (2R,3S,5R)-2-acetoxymethyl-5-{2-[2-(4-tert-butyl-phenyl)-acetylamino]-6-oxo-1,6-dihydro-purin-9-yl}-tetrahydro-furan-3-yl ester 
• 52629-57-9 4'-Methoxy-4-tert.butyldeoxybenzoin 
• 27798-41-0 2-(4-(tert-butyl)phenyl)-1-phenylethanone 
• 34252-96-5 2,3,4-Triphenyl-5-(p-tert.-butylphenyl)-cyclopentadienon 
• 116952-78-4 2-Brom-2-(4-tert-butylphenyl)-N'-tosylacetohydrazid 
• 116952-84-2 2-Brom-2-(4-tert-butylphenyl)-N-tosylacetohydrazonoylchlorid 
• 116952-90-0 N-<2-(4-tert-Butylphenyl)-1-chlorethenyl>-N'-tosyldiazen 
• 22927-07-7 1,2-bis(4-tert-butylphenyl)ethane 
• 98-51-1 4-tert-butyltoluene 
• 64321-35-3 4-(1,1-Dimethylethyl)phenylmethyl ketone 
• 34252-95-4 1-Phenyl-3-(p-tert.-butylphenyl)-propan-2-on 

Relevant articles and documents

Vaulted biaryls in catalysis: A structure-activity relationship guided tour of the immanent domain of the VANOL ligand

The active site in the BOROX catalyst is a chiral polyborate anion (boroxinate) that is assembled in situ from three equivalents of B(OPh) 3 and one of the VANOL ligand by a molecule of substrate. The substrates are bound to the boroxinate by Hbonds to oxygen atoms O1-O3. The effects of introducing substituents at each position of the naphthalene core of the VANOL ligand are systematically investigated in an aziridination reaction. Substituents in the 4,4′- and 8,8′-positions have a negative effect on catalyst performance, whereas, substituents in the 7- and 7′-positions have the biggest impact in a positive direction. VANOL destination: The active site in the BOROX catalyst is a chiral polyborate anion (boroxinate; see figure) that is assembled in situ from three equivalents of B(OPh)3 and one of the VANOL ligand by a molecule of substrate. The effects of introducing substituents at each position of the naphthalene core of the VANOL ligand are systematically investigated in an aziridination reaction. Copyright