52629-60-4 Usage
Classification
Chemical compound
Derivative of silyl enol ether
Usage
Reagent in organic synthesis reactions
Important building block in organic chemistry
Functionality
Ability to substitute an alpha hydrogen atom in carbonyl compounds
Valuable tool for the formation of new carbon-carbon bonds
Application
Preparation of highly functionalized molecules and pharmaceutical compounds
Check Digit Verification of cas no
The CAS Registry Mumber 52629-60-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,2,6,2 and 9 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 52629-60:
(7*5)+(6*2)+(5*6)+(4*2)+(3*9)+(2*6)+(1*0)=124
124 % 10 = 4
So 52629-60-4 is a valid CAS Registry Number.
52629-60-4Relevant articles and documents
Copper(I) tert-butoxide-promoted allylation of β-triphenylsilyl allylic alcohols via 1,3 Csp2-to-o silyl migration
Tsubouchi, Akira,Itoh, Miki,Onishi, Kotaro,Takeda, Takeshi
, p. 1504 - 1508 (2007/10/03)
The substitution of the silyl group in vinylsilanes by an allylic group proceeded when β-triphenylsilylallyl alcohols were treated with copper(I) tert-butoxide and allylic halides. This reaction is the first synthetic application of 1,3 Csp2-to-O silyl migration which provides a useful method for generation of vinyl anion equivalents.
