52630-67-8

Basic information

• Product Name: benzyl 2-acetamido-2-deoxy-4,6-O-(4-methoxybenzylidene)-α-D-glucopyranoside
• Synonyms: benzyl 2-acetamido-2-deoxy-4,6-O-(4-methoxybenzylidene)-α-D-glucopyranoside
• CAS NO: 52630-67-8
• Molecular Weight: 429.47
• Mol File: 52630-67-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: benzyl 2-acetamido-2-deoxy-4,6-O-(4-methoxybenzylidene)-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl 2-acetamido-2-deoxy-4,6-O-(4-methoxybenzylidene)-α-D-glucopyranoside(52630-67-8)
• EPA Substance Registry System: benzyl 2-acetamido-2-deoxy-4,6-O-(4-methoxybenzylidene)-α-D-glucopyranoside(52630-67-8)

Safety Data

• Hazardous Substances Data: 52630-67-8(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 2186-92-7 p-Anisaldehyde dimethyl acetal 
• 13343-62-9 benzyl 2-acetamido-2-deoxy-α-D-glucopyranoside 

Downstream Products

• 94827-29-9 benzyl 2-acetamido-3-O-benzyl-2-deoxy-6-O-(4-methoxybenzyl)-α-D-glucopyranoside 
• 94846-68-1 benzyl 2-acetamido-3-O-benzyl-2-deoxy-4-O-(4-methoxybenzyl)-α-D-glucopyranoside 
• 94827-28-8 benzyl 2-acetamido-3-O-benzyl-2-deoxy-4,6-O-(4-methoxybenzylidene)-α-D-glucopyranoside 

Relevant articles and documents

Regioselective Reductive Ring-opening of 4-Methoxybenzylidene Acetals of Hexopyranosides. Access to a Novel Protecting-group Strategy. Part 1

Reduction of fully protected 4,6-O-(4-methoxybenzylidene) hexopyranosides with sodium cyanoborohydride-trifluoroacetic acid in NN-dimethylformamide, or trimethylsilyl chloride in acetonitrile, gives the 6- and 4-O-(4-methoxybenzyl) ethers, respectively, in good yield and good regioselectivity.The 4-methoxybenzyl ether linkage in products containing benzyl ethers or other protective groups is selectively cleaved upon treatment with cerium(IV) ammonium nitrate in aqueous acetonitrile.