527698-51-7

Basic information

• Product Name: 1-{4-(chloromethyl-dimethyl-silanyl)-1,1-bis-[3-(chloromethyl-dimethyl-silanyl)-propyl]-butyl}-4-methylsulfanyl-benzene
• Synonyms: 1-{4-(chloromethyl-dimethyl-silanyl)-1,1-bis-[3-(chloromethyl-dimethyl-silanyl)-propyl]-butyl}-4-methylsulfanyl-benzene
• CAS NO: 527698-51-7
• Molecular Weight: 584.357
• Mol File: 527698-51-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-{4-(chloromethyl-dimethyl-silanyl)-1,1-bis-[3-(chloromethyl-dimethyl-silanyl)-propyl]-butyl}-4-methylsulfanyl-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-{4-(chloromethyl-dimethyl-silanyl)-1,1-bis-[3-(chloromethyl-dimethyl-silanyl)-propyl]-butyl}-4-methylsulfanyl-benzene(527698-51-7)
• EPA Substance Registry System: 1-{4-(chloromethyl-dimethyl-silanyl)-1,1-bis-[3-(chloromethyl-dimethyl-silanyl)-propyl]-butyl}-4-methylsulfanyl-benzene(527698-51-7)

Safety Data

• Hazardous Substances Data: 527698-51-7(Hazardous Substances Data)

Upstream product

• 3144-74-9 chloromethyldimethylsilane 
• 289699-82-7 1-(1,1-diallyl-but-3-enyl)-4-methylsulfanyl-benzene 

Downstream Products

• 527698-52-8 1-{4-(iodomethyl-dimethyl-silanyl)-1,1-bis-[3-(iodomethyl-dimethyl-silanyl)-propyl]-butyl}-4-methylsulfanyl-benzene 

Relevant articles and documents

Convergent dendron approach using a phenol triallyl building block: Synthesis of a phenol dendron containing 27 allyl termini

A successful convergent dendron synthesis is achieved using a phenol triallyl (AB3) building block by a sequence of reactions consisting of hydrosilylation-phenol protection. The key feature is the hydrosilylation using dimethylchloromethylsilane that avoids the side dehydrohalogenation previously found with linear branches containing β-hydrogens. The advantage of the AB3 building block is the multiplication of the dendron branches by three at each generation, which allows the synthesis of the second-generation 27-allyl phenol dendron.