5277-11-2 Usage
General Description
1-(Dimethylamino)heptane is an organic compound with the molecular formula C9H21N. It is a chemical compound with a seven-carbon chain and a dimethylamino group attached to the first carbon atom. It is a clear, colorless liquid with a faint amine-like odor. 1-(Dimethylamino)heptane is primarily used as a reagent in chemical synthesis and can also be used as a solvent in various industrial processes. It is a highly flammable substance and should be handled with caution. 1-(DIMETHYLAMINO)HEPTANE is not commonly found in commercial products and is primarily used in research and industrial applications.
Check Digit Verification of cas no
The CAS Registry Mumber 5277-11-2 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,2,7 and 7 respectively; the second part has 2 digits, 1 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 5277-11:
(6*5)+(5*2)+(4*7)+(3*7)+(2*1)+(1*1)=92
92 % 10 = 2
So 5277-11-2 is a valid CAS Registry Number.
InChI:InChI=1/C9H21N/c1-4-5-6-7-8-9-10(2)3/h4-9H2,1-3H3
5277-11-2Relevant articles and documents
Methylformate as replacement of syngas in one-pot catalytic synthesis of amines from olefins
Karakhanov, Eduard,Maksimov, Anton,Kardasheva, Yulia,Runova, Elena,Zakharov, Roman,Terenina, Maria,Kenneally, Corey,Arredondo, Victor
, p. 540 - 547 (2014/02/14)
A new general approach for the one-pot hydroaminomethylation of olefins using methylformate as formylating agent instead of synthesis gas (syngas) has been proposed. Herein we report that a Ru-Rh catalytic system demonstrates high activity in a tandem conversion of a series of n-alkenes into amines using methylformate with yields 58-92% (6 h). The selectivity for the normal amine reached 96% with catalysis by the Ru carbonyl complex Ru3(CO) 12, with an overall yield of 55% with respect to amine in this instance. The addition of the Rh complex to Ru catalytic system, sharply increased the hydroaminomethylation rate of both the terminal and internal alkenes and increased the yield of amines to 82-93% (6-12 h). The Royal Society of Chemistry.