52794-07-7

Basic information

• Product Name: 1,7,7-trimethyl-4-phenylbicyclo<2.2.1>hept-2-yl-exo-amine
• CAS NO: 52794-07-7
• Molecular Weight: 229.365
• Mol File: 52794-07-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,7,7-trimethyl-4-phenylbicyclo<2.2.1>hept-2-yl-exo-amine(CAS DataBase Reference)
• NIST Chemistry Reference: 1,7,7-trimethyl-4-phenylbicyclo<2.2.1>hept-2-yl-exo-amine(52794-07-7)
• EPA Substance Registry System: 1,7,7-trimethyl-4-phenylbicyclo<2.2.1>hept-2-yl-exo-amine(52794-07-7)

Safety Data

• Hazardous Substances Data: 52794-07-7(Hazardous Substances Data)

Upstream product

• 35690-40-5 exo-2-acetamido-4-phenylbornane 
• 125161-73-1 4-phenyl-2-isobornylpropionamide 
• 125161-74-2 4-phenyl-2-isobornylmethoxypropionamide 
• 736109-58-3 1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one 
• 7070-01-1 1,7,7-trimethyl-2-phenylbicyclo<2.2.1>heptan-2-exo-ol 

Relevant articles and documents

SYNTHESIS AND RITTER REACTION OF 1,7,7-TRIMETHYL-2-PHENYLBICYCLOHEPTAN-2-EXO-OL

1,7,7-Trimethyl-2-phenylbicycloheptan-2-exo-ol is formed stereospecifically in the reaction of camphor with phenyllithium.The corresponding individual 1,7,7-trimethyl-4-phenylbicyclohept-2-yl-exo-acyl-amines were obtained as a result of the nucleophilic addition of acetonitrile, propionitrile, or methoxypropionitrile to this tertiary alcohol, which takes place in the presence of concentrated sulfuric acid.A scheme is proposed for their formation as a result of rearrangements of the intermediately formed 1,7,7-trimethylbicyclohept-2-yl cation.