52797-55-4

Basic information

• Product Name: Benzenethiol, 2-[(phenylmethyl)amino]-
• CAS NO: 52797-55-4
• Molecular Formula: C13H13NS
• Molecular Weight: 215.319
• Mol File: 52797-55-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenethiol, 2-[(phenylmethyl)amino]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenethiol, 2-[(phenylmethyl)amino]-(52797-55-4)
• EPA Substance Registry System: Benzenethiol, 2-[(phenylmethyl)amino]-(52797-55-4)

Safety Data

• Hazardous Substances Data: 52797-55-4(Hazardous Substances Data)

Upstream product

• 33682-61-0 3-benzylbenzo[d]thiazole-2(3H)-thione 
• 76464-99-8 N-benzyl-2-iodoaniline 
• 883-93-2 2-Phenylbenzothiazole 
• 398469-59-5 2-(N-benzyl)amino-S-benzylthiophenol 
• 6325-92-4 2-(benzylsulfanyl)aniline 
• 137-07-5 2-amino-benzenethiol 
• 77053-20-4 2-(2-propen-1-ylsulfanyl)aniline 
• 1408300-21-9 2-amino-S-cinnamylthiophenol 

Downstream Products

• 102458-15-1 3-benzyl-2-piperidinomethyl-2,3-dihydro-benzothiazole 
• 21223-76-7 3-benzyl-2-(4-dimethylamino-phenyl)-benzothiazolium; chloride 
• 883-93-2 2-Phenylbenzothiazole 
• 56553-71-0 2,2'-disulfanediylbis(N-benzylaniline) 
• 101786-17-8 (3-benzyl-2-methyl-2,3-dihydro-benzothiazol-2-ylmethyl)-dimethyl-amine 

Relevant articles and documents

Copper-catalyzed double c-s bonds formation via different paths: Synthesis of benzothiazoles from n -benzyl-2-iodoaniline and potassium sulfide

A new, highly efficient procedure for the synthesis of benzothiazoles from easily available N-benzyl-2-iodoaniline and potassium sulfide has been developed. The results show copper-catalyzed double C-S bond formation via a traditional cross-coupling reaction and an oxidative cross-coupling reaction.

A new approach to reductive deprotection of thioethers with a low-valent titanium reagent

Low-valent titanium mediated cleavage of carbon-sulphur bond is reported. This has resulted in an efficient and mild protocol for the deprotection of allyl/benzyl thioethers under reductive condition and with good yields. Deprotection can be performed regio- and chemo-selectively in the presence of acid, ester and N-benzyl/allyl functionalities and is general for aliphatic and aromatic precursors.