52834-75-0

Basic information

• Product Name: Methanol, [(4-methylphenyl)thio]-, acetate
• CAS NO: 52834-75-0
• Molecular Formula: C10H12O2S
• Molecular Weight: 196.27
• Mol File: 52834-75-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Methanol, [(4-methylphenyl)thio]-, acetate(CAS DataBase Reference)
• NIST Chemistry Reference: Methanol, [(4-methylphenyl)thio]-, acetate(52834-75-0)
• EPA Substance Registry System: Methanol, [(4-methylphenyl)thio]-, acetate(52834-75-0)

Safety Data

• Hazardous Substances Data: 52834-75-0(Hazardous Substances Data)

Upstream product

• 623-13-2 4-methylphenyl methylsulfide 
• 64-19-7 acetic acid 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 934-72-5 Methyl p-tolyl sulfoxide 
• 108-24-7 acetic anhydride 
• 3996-29-0 2-[(4-methylphenyl)thio]acetic acid 

Downstream Products

• 52716-32-2 methyl-bis-(toluene-4-sulfonylmethyl)-amine 

Relevant articles and documents

Enzyme-promoted kinetic resolution of acetoxymethyl aryl sulfoxides

A simple and efficient method of the synthesis of enantiomerically enriched, unknown acetoxymethyl aryl sulfoxides has been developed which is based on an enzyme-catalyzed hydrolysis of racemic substrates under the kinetic resolution conditions. The hydro

Gold-Catalyzed, Iodine(III)-Mediated Direct Acyloxylation of the Unactivated C(sp3)–H Bonds of Methyl Sulfides

The gold-catalyzed, iodine(III)-mediated direct oxidative acyloxylation of the C(sp3)–H bonds of methyl sulfides for the synthesis of various α-thioaryl and α-thioalkyl ester derivatives was discovered. Bis(acyloxy)iodobenzene proved to be an efficient reagent to activate the sulfur atom as an in situ directing group for α-C(sp3)–H functionalization. The attractive features of this protocol include short reaction times, low catalyst loading, and in situ activation of adjacent C(sp3)–H bonds of the sulfur atom.