5284-10-6Relevant articles and documents
Reaction of Trichloro(o-phenylenedioxy)phosphorane with Four-Coordinate Phosphorus Esters
Khusainova,Reshetkova,Cherkasov
, p. 367 - 369 (2007/10/03)
Reactions of trialkyl phosphates and dialkyl alkenylphosphonates with trichloro(o-phenylenedioxy)phosphorane result in selective replacement of one alkoxy group on the phosphorus by a chlorine atom. Alkylphosphonates react with trichloro(o-phenylenedioxy)phosphorane to give alkyl alkylphosphonochloridates as the major products and small amounts of alkylphosphonic dichlorides.
REACTION OF TRICOORDINATE PHOSPHORUS COMPOUNDS WITH PSEUDOHALOGENS. SCOPE AND MECHANISM
Skowronska, Aleksandra,Krawczyk, Ewa,Burski, Janusz
, p. 233 - 236 (2007/10/02)
The selectivity of sulphur, selenium and oxygen removal from pseudohalogens: phosphorus disulphides 1 and 2, diselenides 3 and oxophosphoranesulphenyl chlorides 4 has been investigated.A mechanistic rationalization is proposed to account for sulphur(selenium)/oxygen extrusion variation as a function of substrates structure and reaction conditions.