52922-10-8

Basic information

• Product Name: 2-methyl-1-phenyl-3-buten-1-ol
• Synonyms: 2-methyl-1-phenyl-3-buten-1-ol
• CAS NO: 52922-10-8
• Molecular Weight: 162.232
• Mol File: 52922-10-8.mol
• Article Data: 231

Chemical Properties

• CAS DataBase Reference: 2-methyl-1-phenyl-3-buten-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-1-phenyl-3-buten-1-ol(52922-10-8)
• EPA Substance Registry System: 2-methyl-1-phenyl-3-buten-1-ol(52922-10-8)

Safety Data

• Hazardous Substances Data: 52922-10-8(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 259150-83-9 (Z)-crotyltrimethoxysilane 
• 6737-11-7 2-acetoxy-3-butene 
• 100-51-6 benzyl alcohol 
• 18147-55-2 but-2-enyltrichlorosilane 
• 1220116-92-6 benzyl but-3-en-2-yl carbonate 
• 95151-35-2 3-buten-2-yl methyl carbonate 
• 22553-90-8 (E)-1-diazobut-2-ene 
• 107-01-7 butene-2 
• 106357-20-4 (R,R)-diisopropyl tartrate (Z)-crotylboronate 
• 590-18-1 (Z)-2-Butene 
• 35998-93-7 tri-n-butylcrotyltin 
• 21969-32-4 crotylmagnesium chloride 
• 99397-92-9 (Z)-(-)-crotylbis(isopinocampheyl)borane 

Downstream Products

• 7087-77-6 (1S,2S)-2-methyl-1-phenyl-propane-1,3-diol 
• 139068-60-3 (2R,3R)-2-methyl-3-phenyl-1,3-propane diol 
• 129065-04-9 (1S,2S)-1-cyclohexyl-2-methylbutan-1-ol 
• 261919-07-7 (3S,5E)-1-phenyl-5-heptene-3-ol 
• 1392302-92-9 (S)-(-)-O-[2-methyl-1-phenyl-3-butene-1-yl]hydroxylamine 
• 1392303-10-4 (3R,4S,5R)-(+)-N-tert-butoxycarbonyl-3-(methoxycarbonylmethyl)-4-methyl-5-phenylisoxazolidine 
• 1392303-11-5 (3S,4S,5R)-(+)-N-tert-butoxycarbonyl-3-(methoxycarbonylmethyl)-4-methyl-5-phenylisoxazolidine 
• 1392303-22-8 methyl (3S,5R)-(+)-3-(tert-butoxycarbamoyl)-5-hydroxy-3-methyl-5-(phenyl)valerate 
• 1446121-69-2 (3R,6R,7S)-((1S,2S)-2-methyl-1-phenylbut-3-enyl) 3,6,7-trihydroxy-6-methylnon-8-enoate 
• 1446121-81-8 (4R,7R,8S,11S,12S,E)-4,7,8-trihydroxy-7,11-dimethyl-12-phenyl-oxacyclododec-9-en-2-one 
• 1446121-91-0 (2S,3S,6S,7R,10R,E)-7,10-dihydroxy-3,7-dimethyl-12-oxo-2-phenyloxa cyclododec-4-en-6-yl acetate 
• 1446121-59-0 (R)-((1S,2S)-2-methyl-1-phenylbut-3-enyl)-3-(tert-butyldimethylsilyloxy)-5-((4R,5S)-2,2,4-trimethyl-5-vinyl-1,3-dioxolan-4-yl)pentanoate 

Relevant articles and documents

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Active bismuth mediated allylation of carbonyls/N-tosyl aldimines and propargylation of aldehydes in water

Abstract: Active bismuth is synthesized by the chemical reduction of bismuth trichloride using freshly prepared sodium stannite solution as the reducing agent at room temperature. The as-synthesized active bismuth is applied as a reagent for the synthesis of homoallyl alcohol/homopropargyl alcohol from allyl bromide/propargyl bromide and carbonyl compounds in water at 50°C. The homoallyl amines are also synthesized from N-tosyl aldimines and allyl bromide using active bismuth reagent in good yields. No assistance of organic co-solvent, co-reagent, phase transfer catalyst or inert atmosphere is required for this reaction. The waste bismuth material obtained after the completion of the organic reaction can be reduced to active bismuth by sodium stannite solution and successfully reused for mediating the allylation of aldehydes. Graphical Abstract:: Synopsis Active bismuth mediated allylation/crotylation of aldehydes is developed in water to get homoallyl alcohols. The method is also applied for the allylation of N-tosyl aldimines and propargylation of aldehydes in water to achieve the homoallyl amines and homopropargyl alcohols, respectively. The reactions do not require the assistance of organic co-solvent, co-reagent, phase transfer catalyst or inert atmosphere.[Figure not available: see fulltext.].