53045-66-2

Basic information

• Product Name: 2-ethenylhexan-1-ol
• Synonyms: 1-hexanol, 2-ethenyl-; 2-Vinylhexan-1-ol
• CAS NO: 53045-66-2
• Molecular Formula: C₈H₁₆O
• Molecular Weight: 128.212
• Mol File: 53045-66-2.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 179.1°C at 760 mmHg
• Flash Point: 67.2°C
• Density: 0.834g/cm³
• Vapor Pressure: 0.286mmHg at 25°C
• Refractive Index: 1.438
• CAS DataBase Reference: 2-ethenylhexan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-ethenylhexan-1-ol(53045-66-2)
• EPA Substance Registry System: 2-ethenylhexan-1-ol(53045-66-2)

Safety Data

• Hazardous Substances Data: 53045-66-2(Hazardous Substances Data)

Upstream product

• 693-03-8 n-butyl magnesium bromide 
• 7045-86-5 2-methyl-4,7-dihydro-1,3-dioxepine 
• 1003-83-4 2,2-dimethyl-4,7-dihydro-1,3-dioxepin 
• 103621-26-7 2-Nitro-2-vinyl-hexan-1-ol 
• 930-22-3 epoxybutene 
• 109-72-8 n-butyllithium 
• 1119-90-0 di-n-butylzinc 

Relevant articles and documents

Regioselective SN2 opening of vinylic epoxides with trialkylzincates and trialkylaluminates

The use of trialkylorganozincates and tetraalkylaluminates allows regioselective SN2 nucleophilic opening of vinylic epoxides. The reaction occurs with an anti-substitution pattern and can be applied to a wide range of substrates. We also show that the solvent and the structure of the epoxide have an influence on the substitution products' ratio. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

Regioselective SN2 opening of α,β-ethylenic epoxides by RLi-BF3 combination

Organolithium reagents effect a regioselective SN2 nucleophilic cleavage of α,β-ethylenic epoxides only when BF3·Et2O is added. The reaction works with a variety of RLi reagents and with cyclic as well as acyclic epoxides. The Royal Society of Chemistry 2000.

NICKEL(II)-CATALYZED ALKYLATION OF 2-METHYL-1,3-DIOXEP-4-ENE BY GRIGNARD REAGENTS: AN EFFICIENT AND SELECTIVE ROUTE TO ALLYLIC ALCOHOLS

Allylic alcohols are formed, in good yields, through the regiocontrolled Cl2Nidppe-catalyzed alkylation of 2-methyl-1,3-dioxep-4-ene by Grignard reagents .Highly pure Z alcohols arise when secondary and tertiary aliphatic Grignards are used.