53059-31-7

Basic information

• Product Name: 1,1'-BIPHENYL, 4'-METHOXY-3-NITRO-
• Synonyms: 1,1'-BIPHENYL, 4'-METHOXY-3-NITRO-;4'-Methoxy-3-nitro-1,1'-biphenyl;1-Methoxy-4-(3-nitrophenyl)benzene
• CAS NO: 53059-31-7
• Molecular Formula: C₁₃H₁₁NO₃
• Molecular Weight: 229.23134
• Mol File: 53059-31-7.mol
• Article Data: 4

Chemical Properties

• Melting Point: 75-77 °C(Solv: methanol (67-56-1))
• Boiling Point: 375.1±35.0 °C(Predicted)
• Appearance: /
• Density: 1.202±0.06 g/cm3(Predicted)
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 1,1'-BIPHENYL, 4'-METHOXY-3-NITRO-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1'-BIPHENYL, 4'-METHOXY-3-NITRO-(53059-31-7)
• EPA Substance Registry System: 1,1'-BIPHENYL, 4'-METHOXY-3-NITRO-(53059-31-7)

Safety Data

• Hazardous Substances Data: 53059-31-7(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Canadian Journal of Chemistry, 45, p. 1539, 1967 DOI: 10.1139/v67-249

Upstream product

• 6311-43-9 3,4'-dinitro-1,1'-biphenyl 
• 124-41-4 sodium methylate 
• 70744-47-7 (p-methoxyphenyl)tri-n-butylstannane 
• 585-79-5 m-nitrobromobenzene 
• 33397-21-6 tris(4-methoxyphenyl)bismuth 
• 13331-27-6 m-nitrobenzene boronic acid 
• 124156-21-4 ethyl (4-methoxyphenylimino)acetate 

Downstream Products

• 53059-30-6 3'-nitro-[1,1'-biphenyl]-4-ol 
• 53059-28-2 4'-methoxy-[1,1'-biphenyl]-3-amine 

Relevant articles and documents

An unusual 1,2-aryl shift in palladium-catalyzed cross-coupling ethoxycarbonylation of arylboronic acids with α-iminoesters

The Pd-catalyzed cross-coupling ethoxycarbonylation of aryl boronic acids with N-aryl-α-iminoesters affords aryl carboxylic esters via carbonyl-imino σ bond cleavage. This unprecedented mode of reaction allows regioselective installation of the ethoxycarbonyl group into target molecules. Mechanism studies have revealed that an unusual 1,2-aryl shift process is involved in the transformation. The Royal Society of Chemistry.

Palladium-catalyzed cross-coupling reactions of dry arenediazonium o-benzenedisulfonimides with aryltin compounds

The palladium-catalyzed cross-coupling reaction between various arenediazonium o-benzenedisulfonimides and aryltin derivatives is described. The procedure is general, easy and gives pure biaryls in good yields (25 examples, average yield 79%). o-Benzenedisulfonimide can be recovered (>80%) and reused to prepare again the starting material. Georg Thieme Verlag Stuttgart.