531515-01-2Relevant articles and documents
Asymmetric synthesis of (+)-1-deoxynojirimycin and (+)-castanospermine
Somfai, Peter,Marchand, Patrice,Torsell, Staffan,Lindstr?m, Ulf M.
, p. 1293 - 1299 (2003)
Asymmetric total syntheses of (+)-1-deoxynojirimycin (1) and (+)-castanospermine (2) are described. Starting from diene 3, the required absolute stereochemistry is introduced by an asymmetric hydroxylation followed by epoxidation. An intramolecular cycliz