5316-81-4

Basic information

• Product Name: 3-Amino-4-phenyl-4-thiazoline-2-thione
• Synonyms: 3-Amino-4-phenyl-4-thiazoline-2-thione
• CAS NO: 5316-81-4
• Molecular Formula: C₉H₈N₂S₂
• Molecular Weight: 208.3
• Mol File: 5316-81-4.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 514.1°C at 760 mmHg
• Flash Point: 264.7°C
• Appearance: /
• Density: 1.554g/cm³
• Vapor Pressure: 1.11E-10mmHg at 25°C
• Refractive Index: 1.644
• CAS DataBase Reference: 3-Amino-4-phenyl-4-thiazoline-2-thione(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Amino-4-phenyl-4-thiazoline-2-thione(5316-81-4)
• EPA Substance Registry System: 3-Amino-4-phenyl-4-thiazoline-2-thione(5316-81-4)

Safety Data

• Hazardous Substances Data: 5316-81-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H11BrClNO2/c15-10-1-7-13(8-2-10)19-9-14(18)17-12-5-3-11(16)4-6-12/h1-8H,9H2,(H,17,18)

Upstream product

• 24521-48-0 5-phenyl-3,4-dihydro-[1,3,4]thiadiazine-2-thione 
• 73798-89-7 phenacyl hydrazinodithioformate 
• 65347-77-5 3-benzoylamino-4-phenyl-3H-thiazole-2-thione 
• 71433-34-6 4-phenyl-3-(toluene-4-sulfonylamino)-3H-thiazole-2-thione 
• 131567-68-5 3-benzoyl-dithiocarbazic acid phenacyl ester 
• 70-11-1 α-bromoacetophenone 
• 71433-33-5 N'-(toluene-4-sulfonyl)-hydrazinecarbodithioic acid 2-oxo-2-phenyl-ethyl ester 

Downstream Products

• 22454-80-4 3-benzylideneamino-4-phenyl-1,3-thiazole-2-thione 
• 65347-77-5 3-benzoylamino-4-phenyl-3H-thiazole-2-thione 
• 23349-44-2 bis(4-phenylthiazol-2-yl) disulfide 
• 120344-58-3 3-Amino-2-benzylthio-4-phenylthiazolium bromide 
• 112085-12-8 5-(4-Nitro-phenyl)-3-phenyl-6H-1,7-dithia-4-aza-3a-azonia-indene; bromide 
• 112085-17-3 3-Amino-2-[2-(4-nitro-phenyl)-2-oxo-ethylsulfanyl]-4-phenyl-thiazol-3-ium; bromide 
• 23149-96-4 4-(p-Methoxybenzylidene)amino-3-phenylthiazoline-2(3H)-thione 
• 112085-13-9 5-Biphenyl-4-yl-3-phenyl-6H-1,7-dithia-4-aza-3a-azonia-indene; bromide 
• 112085-18-4 3-Amino-2-(2-biphenyl-4-yl-2-oxo-ethylsulfanyl)-4-phenyl-thiazol-3-ium; bromide 
• 112085-09-3 3,5-Diphenyl-6H-1,7-dithia-4-aza-3a-azonia-indene; bromide 
• 112085-14-0 3-amino-2-phenacylthio-4-phenylthiazolium bromide 
• 112085-11-7 5-(4-Chloro-phenyl)-3-phenyl-6H-1,7-dithia-4-aza-3a-azonia-indene; bromide 
• 112085-16-2 3-Amino-2-[2-(4-chloro-phenyl)-2-oxo-ethylsulfanyl]-4-phenyl-thiazol-3-ium; bromide 
• 112085-10-6 5-(4-Bromo-phenyl)-3-phenyl-6H-1,7-dithia-4-aza-3a-azonia-indene; bromide 

Relevant articles and documents

FUSED THIAZOLES FROM 3-AMINO-THIAZOLINE-2-THIONES: SYNTHESIS OF PYRAZOLOTHIAZOLE AND THIAZOLO-1,3,4-THIADIAZINE DERIVATIVES

Two approaches for the preparation of a number of pyrazolothiazoles are reported.The first involves reaction of 3-amino-4-phenyl-thiazoline-2-thione 1 with phenacyl bromides to give thiazolo-1,3,4-thiadiazines 2 which by action of triethylamine are converted into the pyrazolothiazoles 4.The second is based on the reaction of 3-amino-2-methylthio-4-phenylthiazolium cation 5 with activated acetonitriles to give 7-substituted 6-amino-3-phenylpyrazolothiazoles 7.