53172-99-9

Basic information

• Product Name: Benzenemethanol, a-[(1,1-dimethylethyl)dimethylsilyl]-
• CAS NO: 53172-99-9
• Molecular Formula: C13H22OSi
• Molecular Weight: 222.403
• Mol File: 53172-99-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-[(1,1-dimethylethyl)dimethylsilyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-[(1,1-dimethylethyl)dimethylsilyl]-(53172-99-9)
• EPA Substance Registry System: Benzenemethanol, a-[(1,1-dimethylethyl)dimethylsilyl]-(53172-99-9)

Safety Data

• Hazardous Substances Data: 53172-99-9(Hazardous Substances Data)

Upstream product

• 75-89-8 2,2,2-trifluoroethanol 
• 131123-36-9 α-t-Butyldimethylsilylbenzyl p-toluenesulfonate 
• 5425-44-5 2-Phenyl-[1,3]dithiane 
• 100-52-7 benzaldehyde 
• 461051-83-2 2-phenyl-2-(tert-butyl dimethylsilyl)-1,3-dithiane 
• 100-51-6 benzyl alcohol 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 648428-84-6 (α,α-bromobenzyl)(tert-butyl)dimethylsilane 
• 435344-57-3 benzyl(tert-butyl)dimethylsilane 
• 100-44-7 benzyl chloride 
• 132868-67-8 (tert-butyldimethylsilyl)(phenyl)methanone 
• 53172-91-1 (benzyloxy)(tert-butyl)dimethylsilane 

Downstream Products

• 648428-53-9 [dimethyl(tert-buthyl)silyl(phenyl)methoxy]trimethylsilane 
• 1330776-76-5 2-hydroxy-5,5-dimethyl-2-(3-oxo-1,3-diphenylpropyl)cyclohexane-1,3-dione 
• 132868-67-8 (tert-butyldimethylsilyl)(phenyl)methanone 
• 1520089-65-9 4-(((tert-butyldimethylsilyl)oxy)(phenyl)methyl)benzonitrile 
• 1520090-01-0 4-(((tert-butyldimethylsilyl)oxy)(phenyl)methyl)pyridine 
• 1520090-05-4 4-(((tert-butyldimethylsilyl)oxy)(phenyl)methyl)-2-methylpyridine 

Relevant articles and documents

Oxidative [1,2]-Brook Rearrangements Exploiting Single-Electron Transfer: Photoredox-Catalyzed Alkylations and Arylations

Oxidative [1,2]-Brook rearrangements via hypervalent silicon intermediates induced by photoredox-catalyzed single-electron transfer have been achieved, permitting the formation of reactive radical species that can engage in alkylations and arylations.

Metal-free relay oxidation: Valuable synthesis of acylsilane and ketones under aerobic oxidation

In this letter, an example of interesting metal-free relay air oxidation of -hydroxysilanes, promoted by the hydroperoxidated carbonyl compounds derived from the Michael reaction of 5,5-dimethylcyclohexane-1,3-dione and chalcone, is reported. A series of aromatic acylsilanes with TBDPS were obtained in promising isolated yields. In addition, as an extension of the relay oxidation under aerobic conditions, this catalyst-free relay oxidation induced by diketone can be applied to the oxidation of general aromatic alcohols (up to 75% yield). Georg Thieme Verlag Stuttgart · New York.

Rates and Mechanism for the Solvolyses of 2,2-Dimethyl-2-sila-1-indanyl Bromide and α-Trialkylsilylbenzyl p-Toluenesulfonates. α-Silicon Effect on the Stability of Benzylic Cations in Solution

α-Silicon effect on the benzylic solvolysis has been investigated.The solvolysis of 2,2-dimethyl-2-sila-1-indanyl bromide in aq acetone exhibits a linear response to the solvent ionizing power YBr, with a slope m close to unity (m = 0.93) and g