533888-83-4

Basic information

• Product Name: isopropyl {[3,5-bis(trifluoromethyl)phenyl]thio}acetate
• Synonyms: isopropyl {[3,5-bis(trifluoromethyl)phenyl]thio}acetate
• CAS NO: 533888-83-4
• Molecular Weight: 346.293
• Mol File: 533888-83-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: isopropyl {[3,5-bis(trifluoromethyl)phenyl]thio}acetate(CAS DataBase Reference)
• NIST Chemistry Reference: isopropyl {[3,5-bis(trifluoromethyl)phenyl]thio}acetate(533888-83-4)
• EPA Substance Registry System: isopropyl {[3,5-bis(trifluoromethyl)phenyl]thio}acetate(533888-83-4)

Safety Data

• Hazardous Substances Data: 533888-83-4(Hazardous Substances Data)

Upstream product

• 1427308-57-3 C₁₀H₆F₆O₂S 
• 546-68-9 titanium(IV) isopropylate 
• 1427308-53-9 C₁₂H₁₀F₆O₂S 
• 107-18-6 allyl alcohol 
• 29921-57-1 isopropyl 2-bromoacetate 
• 130783-02-7 3,5-bis(trifluoromethyl)thiophenol 

Downstream Products

• 533889-38-2 isopropyl 2-{[3,5-bis(trifluoromethyl)phenyl]sulfonyl}-5-methyl-2-(3-methylbut-2-enyl)hex-4-enoate 
• 533889-21-3 isopropyl 2-allyl-2-{[3,5-bis(trifluororomethyl)phenyl]sulfonyl}pent-4-enoate 
• 404825-91-8 isopropyl 2-benzyl-2-{[3,5-bis(trifluororomethyl)phenyl]sulfonyl}-3-phenylpropanoate 
• 404825-83-8 isopropyl {[3,5-bis(trifluoromethyl)phenyl]sulfonyl}acetate 

Relevant articles and documents

Mild, rapid, and inexpensive microwave-assisted synthesis of allylic and propargylic esters

A variety of allylic and propargylic esters were rapidly prepared via microwave heating of their corresponding mixed anhydride derived from pivaloyl chloride. The reaction conditions were modified to account for the sterics of the alcohol and the electronics of the carboxylic acid. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications to view the free supplemental file.

π-Deficient α-arylsulfonyl esters as soft nucleophiles in organic synthesis

Different π-deficient arylsulfonyl groups have been studied as candidates for the stabilization of α-sulfonyl esters. The 3,5-bis(trifluoromethyl)phenylsulfonyl group has been shown to be the best substituent for the stereoselective synthesis of E-aconitates by a dialkylation-dehydrosulfinylation integrated process under PTC conditions using K2CO3 as base.