53498-47-8

Basic information

• Product Name: N-(4-VINYL-PHENYL)-ACETAMIDE
• Synonyms: N-(4-VINYL-PHENYL)-ACETAMIDE;AcetaMide, N-(4-ethenylphenyl)-;N-(4-ethenylphenyl)acetamide
• CAS NO: 53498-47-8
• Molecular Formula: C₁₀H₁₁NO
• Molecular Weight: 161.20044
• Mol File: 53498-47-8.mol
• Article Data: 20

Chemical Properties

• Melting Point: 133-134 °C(Solv: isopropanol (67-63-0))
• Boiling Point: 344.8±21.0 °C(Predicted)
• Appearance: /
• Density: 1.085±0.06 g/cm3(Predicted)
• PKA: 14.91±0.70(Predicted)
• CAS DataBase Reference: N-(4-VINYL-PHENYL)-ACETAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-VINYL-PHENYL)-ACETAMIDE(53498-47-8)
• EPA Substance Registry System: N-(4-VINYL-PHENYL)-ACETAMIDE(53498-47-8)

Safety Data

• Hazardous Substances Data: 53498-47-8(Hazardous Substances Data)

Upstream product

• 1520-21-4 4-vinyl benzylamine 
• 108-24-7 acetic anhydride 
• 75-36-5 acetyl chloride 
• 2554-06-5 2,4,6,8-tetramethyl-2,4,6,8-tetravinyl-cyclotetrasiloxane 
• 103-88-8 4-bromoacetanilide 
• 100-13-0 4-nitrostyrene 
• 100-27-6 2-(4-nitrophenyl)ethanol 
• 35447-83-7 N-(4-ethynylphenyl)acetamide 
• 141-78-6 ethyl acetate 
• 539-03-7 N-(4-chlorophenyl)acetamide 
• 79-10-7 acrylic acid 
• 74-85-1 ethene 
• 622-50-4 4-Acetamido-1-iodobenzene 
• 2719-21-3 4-(N-acetylamino)acetophenone 

Downstream Products

• 122240-37-3 (C₆H₅)3SnCH₂CH₂C₆H₄-p-NHCOCH₃ 
• 99984-80-2 4'-acetamido-2-thiocyanatoacetophenone 
• 380365-27-5 2-(4-{(1E)-2-[4-(acetylamino)phenyl]vinyl}phenyl)acetic acid 
• 756763-85-6 2-{4-[(1E)-2-(4-aminophenyl)vinyl]phenyl}acetic acid 
• 1201553-46-9 N-(4-(undecan-2-yl)phenyl)acetamide 
• 1400999-72-5 1-(4-acetamidophenyl)-3,3,3-trifluoropropyl 2-iodobenzoate 
• 1449325-74-9 N-(4-(1-methoxy-2-phenylethyl)phenyl)acetamide 

Relevant articles and documents

Nickel-Catalyzed Reductive Cross-Coupling of Aryl Bromides with Vinyl Acetate in Dimethyl Isosorbide as a Sustainable Solvent

A nickel-catalyzed reductive cross-coupling has been achieved using (hetero)aryl bromides and vinyl acetate as the coupling partners. This mild, applicable method provides a reliable access to a variety of vinyl arenes, heteroarenes, and benzoheterocycles, which should expand the chemical space of precursors to fine chemicals and polymers. Importantly, a sustainable solvent, dimethyl isosorbide, is used, making this protocol more attractive from the point of view of green chemistry.

Selective hydrodeoxygenation of hydroxyacetophenones to ethyl-substituted phenol derivatives using a FeRu?SILP catalyst

The selective hydrodeoxygenation of hydroxyacetophenone derivatives is achieved opening a versatile pathway for the production of valuable substituted ethylphenols from readily available substrates. Bimetallic iron ruthenium nanoparticles immobilized on an imidazolium-based supported ionic liquid phase (Fe25Ru75?SILP) show high activity and stability for a broad range of substrates without acidic co-catalysts. This journal is

Synthesis and Catalytic Applications of [N,N]-Pyrrole Ligands for the Regioselective Synthesis of Styrene Derivatives

We report the synthesis of two [N,N]-donor ligands (5 a–b) containing a 2-chalcogenazoline as the structural motif. These compounds were synthesized from a common intermediate Fischer type aminocarbene complex (3). The palladium-complexes of these [N,N]-donor ligands were successfully used as catalytic precursors in the Mizoroki-Heck coupling reaction between aryl halides and methyl acrylate, styrene and ethylene. For methyl acrylates, high yields with TOF values between 0.6 and 5.5×105 h?1 were obtained. In the case of ethylene, we reached high regioselectivities to obtain a diversity of styrene derivatives under soft pressure conditions, with good values of TON and TOF. (Figure presented.).