535994-37-7Relevant articles and documents
A ring closing metathesis strategy for carbapyranosides of xylose and arabinose
Mattis, Clayton E.,Mootoo, David R.
, p. 143 - 147 (2016)
The synthesis of β-carba-xylo and arabino pyranosides of cholestanol is described. The synthetic strategy, which is analogous to the Postema approach to C-glycosides, centers on the ring closing metathesis of an enol ether-alkene precursor to give a cycli
Stereoselective Strecker and carbamate annulation methodology for the synthesis of 1-amino-1,2,5-trideoxy-2,5-imino-L-iditol
Win-Mason, Anna L.,Dangerfield, Emma M.,Tyler, Peter C.,Stocker, Bridget L.,Timmer, Mattie S. M.
experimental part, p. 4008 - 4014 (2011/09/15)
An efficient and highly stereoselective synthesis of L-ido-aminoiminosugar 3 has been described. Key in the synthesis is the application of a diastereoselective Strecker reaction and the extension of our carbamate annulation methodology to protected and functionalized alkenylamines. In addition, the identification of the primary iodide as a key intermediate during the carbamate annulation reaction provides insight into the mechanism of this reaction. Copyright