53620-54-5Relevant articles and documents
Synthesis, Surface Activities and Toluene Solubilization by Amine-oxide Gemini Surfactants
Liu, Hongqin,Hu, Jun,Xu, Baocai,Zhao, Tingting,Shi, Guoying,Zhang, Guiju
, p. 673 - 680 (2016/07/06)
A series of amine-oxide gemini surfactants featuring amide groups [N, N’-dimethyl-N, N’-bis(2-alkylamideethyl)-ethylenediamine oxide (alkyl?=?C11H23, C13H27, C15H31, C17H35)] have been synthesized via a three-step synthetic route, and their chemical structures were confirmed by mass spectra, FTIR and 1H-NMR spectra. The surface activities of these compounds have been measured. The results show that these synthesized amine-oxide gemini surfactants reduced the surface tension of water to a minimum value of approximately 26.91?mN?m?1 at a concentration of 2.92?×?10?5mol?L?1. Furthermore, their critical micelle concentration (CMC) values and solubilization of toluene decrease with an increase of the hydrophobic chain length from 12 to 18. Isoelectric point measurements revealed that their pI values range from 4.0 to 10.5.