53829-09-7 Usage
Description
[4,4'-Bipyridine]-2,2'-dicarbonitrile, with the molecular formula C14H8N4, is a chemical compound derived from the organic compound bipyridine. It is characterized by its two cyano (CN) functional groups and is known for its ability to form coordination complexes with transition metals. This versatile compound plays a significant role in the advancement of various scientific disciplines, including organic chemistry, catalytic reactions, supramolecular chemistry, and the development of organic electronic devices and metal-organic frameworks.
Uses
Used in Organic Chemistry:
[4,4'-Bipyridine]-2,2'-dicarbonitrile is used as a building block for the synthesis of various complex molecules and materials. Its unique structure and functional groups make it a valuable component in the creation of new organic compounds.
Used in Catalytic Reactions:
As a ligand, [4,4'-Bipyridine]-2,2'-dicarbonitrile forms coordination complexes with transition metals, which are essential in catalytic reactions. These complexes enhance the efficiency and selectivity of various chemical transformations.
Used in Supramolecular Chemistry:
The ability of [4,4'-Bipyridine]-2,2'-dicarbonitrile to form coordination complexes also makes it useful in supramolecular chemistry. It can be employed to construct complex molecular architectures and study their properties and interactions.
Used in the Development of Organic Electronic Devices:
[4,4'-Bipyridine]-2,2'-dicarbonitrile has potential applications in the development of organic electronic devices, such as organic light-emitting diodes (OLEDs) and organic field-effect transistors (OFETs), due to its electronic properties and ability to form complexes with metals.
Used in Metal-Organic Frameworks (MOFs):
This chemical compound is also used as a ligand in the construction of metal-organic frameworks. MOFs are porous materials with potential applications in gas storage, separation, and catalysis, and [4,4'-Bipyridine]-2,2'-dicarbonitrile contributes to their structural diversity and functionality.
Check Digit Verification of cas no
The CAS Registry Mumber 53829-09-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,3,8,2 and 9 respectively; the second part has 2 digits, 0 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 53829-09:
(7*5)+(6*3)+(5*8)+(4*2)+(3*9)+(2*0)+(1*9)=137
137 % 10 = 7
So 53829-09-7 is a valid CAS Registry Number.
53829-09-7Relevant articles and documents
Selective formation of HCO2(1-) and C2O4(2-) in electrochemical reduction of CO2 catalyzed by mono- and di-nuclear ruthenium complexes
Ali, Md. Meser,Sato, Hiroyasu,Mizukawa, Tetsunori,Tsuge, Kiyoshi,Haga, Masa-aki,Tanaka, Koji
, p. 249 - 250 (1998)
Electrochemical reduction of carbon dioxide catalyzed by mono- and di-nuclear ruthenium complexes produced HCO2H with trace amounts of CO and C2O4(2-) in the presence and absence of H2O, respectively, in MeCN.
Novel chiral oxazoline ligands for potential charge-transfer effects in the Rh(I)-catalysed enantioselective hydrosilylation
Brunner, Henri,Stoeriko, Reinhard,Rominger, Frank
, p. 771 - 781 (2007/10/03)
Novel 2-(4,4′-bipyridin-2-yl)oxazolines, bearing a chiral oxazoline moiety, were synthesised starting from 4,4′-bipyridine and selectively monomethylated in the N′-position. After coordination to rhodium these electron-poor ligands are supposed to exhibit charge-transfer effects with electron-donating substrates in the Rh(I)-catalysed enantioselective hydrosilylation (see next publication). Similar effects were expected from 4,4′-bipyridine- and pyrazine-bisoxazolines after complexation with rhodium. For comparison 2-(4-phenylpyridin-2-yl)oxazoline ligands were synthesised. Rh(I)-complexes of selected ligands were prepared and characterised, including an X-ray structure analysis.
