53907-76-9

Basic information

• Product Name: 1,1-Dimethylbutyloxirane
• Synonyms: 1,1-Dimethylbutyloxirane;1,2-Epoxy-3,3-dimethylhexane
• CAS NO: 53907-76-9
• Molecular Formula: C8H16O
• Molecular Weight: 128.21
• Mol File: 53907-76-9.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 139.0±8.0 °C(Predicted)
• Appearance: /
• Density: 0.893±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 1,1-Dimethylbutyloxirane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-Dimethylbutyloxirane(53907-76-9)
• EPA Substance Registry System: 1,1-Dimethylbutyloxirane(53907-76-9)

Safety Data

• Hazardous Substances Data: 53907-76-9(Hazardous Substances Data)

Upstream product

• 3404-77-1 3,3-dimethylhex-1-ene 

Relevant articles and documents

Co(II) Schiff base Complexes Encapsulated in the Nanopores of Zeolite Y as Heterogeneous Catalysts for Selective Epoxidation of Alkenes with Molecular Oxygen

Abstract: Co(II) macrocyclic Schiff base complex nanoparticles have been encapsulated in the nanopores of zeolite Y. The new Schiff base complexes entrapped in the nanoreactor of zeolite Y were characterized by several techniques: chemical analysis and spectroscopic methods (FT-IR, XRD, and DRS). These complexes (neat and encapsulated) were used for epoxidation of alkenes with O2 as oxidant in different solvents. The catalyst demonstrated excellent activity for a variety of alkenes in a mild, inexpensive and efficient protocol. Reaction parameters including temperature, catalyst amount and solvent were screened by reaction time. The recycling experiment results indicated that the catalysts were highly stable and maintained activity and selectivity even after being used for five cycles.

Schiff base complexes of Mo(VI) immobilized on functionalized graphene oxide nano-sheets for the catalytic epoxidation of alkenes

Mo(VI) tetradentate Schiff base complexes were covalently immobilized onto chemically functionalized graphene oxide (GO) using 3-(tri-methoxysilyl) propylamine as a coupler. The resulting heterogeneous catalysts have been characterized by FTIR, DRS, XRD, SEM, TGA, and atomic absorption spectroscopy (AAS). These catalysts were applied in epoxidation of cyclooctene and other olefins. The catalytic procedures with all catalysts were optimized for different parameters such as oxidant, solvent and temperature. Recycling results indicated that the catalysts were highly stable and maintained activity and selectivity even after being used for five cycles.

A simple and efficient method for epoxidation of terminal alkenes

The use of a catalytic amount of 3-cyanopyridine in the methyltrioxorhenium catalysed epoxidation of terminal alkenes with aqueous hydrogen peroxide speeds turnover, which results in the formation of many functionalized epoxides in high yields.