53907-92-9Relevant articles and documents
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Frankland, E.
, p. 363 - 381 (1862)
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General synthesis of alkylalkenylalkynylboranes via haloboranes
Brown, Herbert C.,Basavaiah,Bhat
, p. 1468 - 1470 (2008/10/08)
Methyl alkylalkenylborinates, obtained via hydroboration of alkynes with alkylbromoboranes, followed by methanolysis, react with alkynyllrthium reagents in THF to form the corresponding ate complexes, which, on treatment with 1.33 equiv of BF3·OEt2, produce the desired alkylalkenylalkynylboranes, thus providing a convenient and simple synthesis of these hitherto inaccessible organoboranes.