54034-47-8Relevant articles and documents
Sulfur-mediated difunctionalization of internal and terminal alkynes for the synthesis of α-acetoxy ketones
Li, Pingfan,Zhang, Zhong
supporting information, (2020/02/13)
The sulfur-mediated difunctionalization of alkynes is reported to give α-acetoxy ketones in a one-pot operation under mild conditions with 19–92% yield. By using wet potassium acetate as both the aqueous base and nucleophilic reagent, both terminal alkynes and internal alkynes could be converted into the α-acetoxy ketone products.
An efficient method for the α-acetoxylation of ketones
Sheng, Jinmei,Li, Xiaolong,Tang, Mingfang,Gao, Botao,Huang, Guosheng
, p. 1165 - 1168 (2008/02/03)
α-Acetoxylation of ketones catalyzed by iodobenzene using 30% aqueous hydrogen peroxide and acetic anhydride as the oxidant is an effective and economical method for the preparation of a-acetoxy ketones. The reaction gave the products in good yields witho
Synthesis of Oxazoles by the Reaction of Ketones with Iron(III) Solvates of Nitriles
Kotani, Eiichi,Kobayashi, Shigeki,Adachi, Mayumi,Tsujioka, Toshiyuki,Nakamura, Kouji,Tobinaga, Seisho
, p. 606 - 609 (2007/10/02)
Oxazoles having functionalized carbon substituents at the C-2 position were synthesized in one step by the oxidation of ketones with iron(III) solvates of nitriles, i.e., Fe(RCN)6(ClO4)3(solvate A) or Fe(RCN)6)FeCl4)3(solvate B), in the corresponding nitriles.Keywords oxazole; ketone; oxidation; nitrile; iron(III) nitrile solvate
