54091-04-2

Basic information

• Product Name: N-(oxodiphenyl-λ⁶-sulfanylidene)benzamide
• Synonyms: N-(oxodiphenyl-λ⁶-sulfanylidene)benzamide
• CAS NO: 54091-04-2
• Molecular Weight: 321.4
• Mol File: 54091-04-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: N-(oxodiphenyl-λ⁶-sulfanylidene)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(oxodiphenyl-λ⁶-sulfanylidene)benzamide(54091-04-2)
• EPA Substance Registry System: N-(oxodiphenyl-λ⁶-sulfanylidene)benzamide(54091-04-2)

Safety Data

• Hazardous Substances Data: 54091-04-2(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 67-66-3 chloroform 
• 22731-83-5 S,S-diphenylsulphoximine 
• 611-70-1 phenyl isopropyl ketone 
• 945-51-7 1,1'-sulfinylbisbenzene 
• 611-73-4 Benzoylformic acid 
• 108-88-3 toluene 
• 98-86-2 acetophenone 

Relevant articles and documents

Visible light-induced C-C bond cleavage in a multicomponent reaction cascade allowing acylations of sulfoximines with ketones

Visible light induces C-C-bond cleavage reactions of ketones, which can be utilized forN-acylations of sulfoximines. No (photo)catalyst is required, and the reactions occur at ambient temperature in air. The substrate scope is broad for both ketones and sulfoximines. For convertingNH-sulfoximines, the presence of NBS is essential.

Palladium catalyzed aroylation of NH-sulfoximines with aryl halides using chloroform as the CO precursor

A palladium-catalyzed aroylation of NH-sulfoximines for the efficient synthesis of N-aroyl sulfoximines from aryl halides and chloroform has been developed. The mild reaction conditions (temperature, catalyst loading) and the use of a CO surrogate render this transformation a useful method for the synthesis of N-aroyl sulfoximines from available feedstock.

Transition metal-free aroylation of NH-sulfoximines with methyl arenes

A novel protocol towards N-aroylated sulfoximines from NH-sulfoximines and methyl arenes was herein demonstrated. The reaction took place in the presence of elemental iodine, requiring no external organic solvents, transition metal-catalysts or ligands. The aroylated products were obtained from the oxidative transformation in moderate to excellent yields (up to 94% yield) with a broad substrate scope (35 examples) through a radical pathway.