54313-18-7 Usage
Description
1-Methoxy-2-(3-methyl-2-butenyl)-9H-carbazole-3-carbaldehyde is an organic compound derived from the alkaloid found in Clausena indica Olivo. It crystallizes from a mixture of CH2Cl2 and hexane, forming colorless plates. 1-Methoxy-2-(3-methyl-2-butenyl)-9H-carbazole-3-carbaldehyde exhibits a complex ultraviolet spectrum in EtOH, with absorption maxima at 237, 247, 275, 294, and 330 nm.
Uses
Used in Pharmaceutical Industry:
1-Methoxy-2-(3-methyl-2-butenyl)-9H-carbazole-3-carbaldehyde is used as a pharmaceutical compound for its potential therapeutic applications. 1-Methoxy-2-(3-methyl-2-butenyl)-9H-carbazole-3-carbaldehyde's unique structure and absorption properties make it a candidate for further research and development in the field of medicine.
Used in Chemical Research:
This carbazole derivative is used as a research compound in the field of organic chemistry. Its complex ultraviolet spectrum and unique structural features make it an interesting subject for studying chemical reactions, synthesis, and potential applications in various chemical processes.
Used in Material Science:
1-Methoxy-2-(3-methyl-2-butenyl)-9H-carbazole-3-carbaldehyde may be utilized in material science for the development of new materials with specific optical, electronic, or structural properties. Its unique absorption characteristics could be exploited in the design of advanced materials for various applications, such as sensors, optoelectronics, or coatings.
References
Joshi, Gawad, Ind. J. Chem., 12, 437 (1974)*INTEG ERRESSINE
This alkaloid has recently been isolated from a further species, Retanilla
ephedra, by South American investigators.Bhakhun et ai., Rev. Latinoamer. Quim., 5, 158 (1974)
Check Digit Verification of cas no
The CAS Registry Mumber 54313-18-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,4,3,1 and 3 respectively; the second part has 2 digits, 1 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 54313-18:
(7*5)+(6*4)+(5*3)+(4*1)+(3*3)+(2*1)+(1*8)=97
97 % 10 = 7
So 54313-18-7 is a valid CAS Registry Number.
54313-18-7Relevant articles and documents
Divergent Syntheses of Carbazole Alkaloids Clausenapin, Indizoline, Claulansine M, and Clausenaline D
Liu, Yizhen,Guo, Yanqin,Ji, Feixiang,Gao, Dong,Song, Chuanjun,Chang, Junbiao
, p. 4310 - 4315 (2016)
We described the first total syntheses of clausenapin, indizoline, claulansine M, and a novel synthetic route to clausenaline D via divergent method. Key steps involved TFAA-mediated intramolecular acylation to construct the carbazole core and subsequent Claisen rearrangement to generate key intermediates for further elaboration to target molecules.
Enantioselective Alkoxycyclization of 1,6-Enynes with Gold(I)-Cavitands: Total Synthesis of Mafaicheenamine C
Martín-Torres, Inmaculada,Ogalla, Gala,Yang, Jin-Ming,Rinaldi, Antonia,Echavarren, Antonio M.
, p. 9339 - 9344 (2021/03/18)
Chiral gold(I)-cavitand complexes have been developed for the enantioselective alkoxycyclization of 1,6-enynes. This enantioselective cyclization has been applied for the first total synthesis of carbazole alkaloid (+)-mafaicheenamine C and its enantiomer, establishing its configuration as R. The cavity effect was also evaluated in the cycloisomerization of dienynes. A combination of experiments and theoretical studies demonstrates that the cavity of the gold(I) complexes forces the enynes to adopt constrained conformations, which results in the high observed regio- and stereoselectivities.
