54415-31-5Relevant articles and documents
Photochemistry of 3H-furo[3,4-c]pyrazoles and 3H-thieno[3,4-c]pyrazoles
Payne, Alan D.
, p. 9316 - 9321 (2013)
The first examples of 3H-furo[3,4-c]pyrazoles and 3H-thieno[3,4-c]pyrazoles were prepared in an attempt to isolate examples of cyclopropane-fused thiophenes and furans. Adducts of acetylenic ketones and 2-diazopropane were reacted with 10-camphorsulfonic acid or phosphorus pentasulfide to produce the title compounds. Photolysis of these compounds did not give the cyclopropane-fused products rather an unreported photochemical fragmentation was observed.
Selective oxidation of acetylenic 1,4-diols with dioxiranes in comparison with the methyltrioxorhenium-hydrogen peroxide oxidant
D'Accolti, Lucia,Fiorentino, Michele,Fusco, Caterina,Crupi, Pasquale,Curci, Ruggero
, p. 8575 - 8578 (2007/10/03)
Dimethyldioxirane (DMD) and its trifluoro analog (TFD) were employed to achieve selectively the direct transformation of diol 3a and of diol 3b into the corresponding carbonyls. The results are compared with oxidations using methyltrioxorhenium (MTO)/85%
A convenient synthesis of α,β-acetylenic ketones
Li,Wai Man Fong,Chao,Fung,Williams
, p. 4087 - 4090 (2007/10/03)
-