54458-95-6

Basic information

• Product Name: (E)-2-(cyclohex-1-en-1-yl)-2-(3-(4-methoxyphenyl)allyl)malononitrile
• Synonyms: (E)-2-(cyclohex-1-en-1-yl)-2-(3-(4-methoxyphenyl)allyl)malononitrile
• CAS NO: 54458-95-6
• Molecular Weight: 292.381
• Mol File: 54458-95-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-2-(cyclohex-1-en-1-yl)-2-(3-(4-methoxyphenyl)allyl)malononitrile(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-(cyclohex-1-en-1-yl)-2-(3-(4-methoxyphenyl)allyl)malononitrile(54458-95-6)
• EPA Substance Registry System: (E)-2-(cyclohex-1-en-1-yl)-2-(3-(4-methoxyphenyl)allyl)malononitrile(54458-95-6)

Safety Data

• Hazardous Substances Data: 54458-95-6(Hazardous Substances Data)

Upstream product

• 4354-73-8 2-(cyclohexylidene)malononitrile 
• 53484-54-1 3-(4-methoxyphenyl)prop-2-enyl acetate 
• 108-94-1 cyclohexanone 
• 51410-44-7 1-(4-methoxylphenyl)-2-propen-1-ol 
• 94607-41-7 (E)-1-(4-methoxyphenyl)-3-chloropropene 
• 123-11-5 4-methoxy-benzaldehyde 

Downstream Products

• 54459-03-9 2-{2-[1-(4-Methoxy-phenyl)-allyl]-cyclohexylidene}-malononitrile 

Relevant articles and documents

Factors Governing and Application of the Cope Rearrangement of 3,3-Dicyano-1,5-dienes and Related Studies

Cope and co-workers reported the [3,3] rearrangement of 3,3-dicyano-1,5-dienes in the early 1940s ( The Cope rearrangement ). However, these original substrates have remained largely unstudied until recently. Herein we explore styrene-deconjugating Cope rearrangements, a diastereoselective Cope rearrangement/deconjugative α-allylation sequence, and factors governing α- vs γ-allylation regioselectivity of Knoevenagel adduct allyl anions. Ultimately, these studies result in the synthesis of diverse and functionally dense polycycloalkane frameworks from abundant reagents using simple chemistry.