54535-13-6

Basic information

• Product Name: 2-(p-tolylamino-methylene)-malonic acid monoethyl ester
• Synonyms: 2-(p-tolylamino-methylene)-malonic acid monoethyl ester
• CAS NO: 54535-13-6
• Molecular Weight: 249.266
• Mol File: 54535-13-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(p-tolylamino-methylene)-malonic acid monoethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(p-tolylamino-methylene)-malonic acid monoethyl ester(54535-13-6)
• EPA Substance Registry System: 2-(p-tolylamino-methylene)-malonic acid monoethyl ester(54535-13-6)

Safety Data

• Hazardous Substances Data: 54535-13-6(Hazardous Substances Data)

Upstream product

• 19056-84-9 diethyl 2-[(p-tolylamino)methylidene]malonate 
• 87-13-8 diethyl 2-ethoxymethylenemalonate 
• 623-10-9 N-(4-methylphenyl)hydroxylamine 
• 54535-08-9 5-oxo-2-p-tolyl-2,5-dihydro-isoxazole-4-carboxylic acid ethyl ester 

Downstream Products

• 19056-84-9 diethyl 2-[(p-tolylamino)methylidene]malonate 
• 54535-19-2 2-[1-p-Tolylamino-meth-(E)-ylidene]-malonic acid ethyl ester methyl ester 

Relevant articles and documents

Lewis acid mediated selective monohydrolysis of geminal diesters: Synthesis of functionalized malonic acid half esters

Geminal diesters, N-alkyl/aryl-2,2-bis(ethoxycarbonyl)vinylamines, were found to undergo selective hydrolysis in the presence of BF3· OEt2 at room temperature to give the corresponding half esters. Neighboring group participation by