54589-54-7Relevant articles and documents
A versatile and convenient method for the functionalization of porphyrins
Didier, Amandine,Michaudet, Lydie,Ricard, David,Baveux-Chambeno?t, Valérie,Richard, Philippe,Boitrel, Bernard
, p. 1927 - 1926 (2001)
The condensation of 3-(chloromethyl)benzoyl chloride with different atropisomers of meso-(tetra-o-aminophenyl)porphyrin (TAPP), followed by the reaction of a series of nucleophilic reagents leads, among others, to precursors of biomimetic models of heme p
Pd-catalyzed α-arylation of nitriles and esters and γ-arylation of unsaturated nitriles with TMPZnCl?LiCl
Duez, Stephanie,Bernhardt, Sebastian,Heppekausen, Johannes,Fleming, Fraser F.,Knochel, Paul
supporting information; experimental part, p. 1690 - 1693 (2011/05/06)
Using TMPZnCl?LiCl as a kinetically highly active base, nitriles and esters undergo a Pd-catalyzed α-arylation under mild conditions. Remarkably, in the case of α,β- or β,γ-unsaturated nitriles, a regioselective γ-arylation or a γ-alkenylation is observed.
Propargylic sulfone-armed lariat crown ethers: Alkali metal ion- regulated DNA cleavage agents
McPhee, Mark M.,Kern, Jonathan T.,Hoster, Ben C.,Kerwin, Sean M.
, p. 98 - 118 (2007/10/03)
Alkali metal ion concentrations within cells are regulated during the cell cycle and may be significantly altered in cancer cells versus normal cells. Thus, the selective destruction of cancer cells might be achieved by agents that marry alkali metal ion
