5459-38-1Relevant articles and documents
Modified acrylate, preparation method thereof and application of modified acrylate in preparation of conductive adhesive
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Paragraph 0061-0066, (2019/11/28)
The invention discloses modified acrylate, a preparation method thereof and application of modified acrylate in preparation of a conductive adhesive. Hydroxyl groups in a polyol acrylate monomer is converted into alpha-H-containing acetal groups so as to obtain the modified acrylate. The modified acrylate obtained through reduction of hydroxyl groups has low viscosity, and can be effectively usedas a reactive diluent in a photo-cured coating formula, and since the modified acrylate contains the alpha-H-containing acetal groups which can promote photopolymerization activity, the photo-curing activity can be improved, so that photocrosslinking is promoted without addition of a hydrogenation donor assistant, and the problem of oxygen inhibition is avoided. When the modified acrylate is applied to preparation of a photo-cured composition, the prepared photo-cured composition has easy curing and fast surface drying; and the invention also provides a method for preparing the alpha-H-containing acetal groups through a reaction between enol ether and hydroxyl groups of the polyol acrylate monomer, and provides application of the modified acrylate in preparation of the photo-cured composition and the conductive adhesive of the photo-cured composition.
PH-SENSITIVE NANOPARTICLES FOR DETECTING AND PREVENTING FOOD SPOILAGE
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Paragraph 0122; 0123, (2018/10/21)
Nanoparticles and compositions thereof are provided for detecting and/or preventing food spoilage. Methods of making the nanoparticles and compositions, and methods of using the nanoparticles and compositions, e.g. in food packaging, are also provided. The nanoparticles can have a hydrophobic core containing a hydrophobic active agent, e.g. a hydrophobic dye and/or an antimicrobial agent, for detecting and/or preventing food spoilage. The nanoparticles can also have a copolymer of a hydrophobic polymer repeat unit, e.g. styrene or lactic acid, and a pH responsive dendrimer repeat unit. The pH responsive dendrimer repeat unit can have a pH responsive amine core having a plurality of branched acrylate arms extending therefrom. The nanoparticles can be chemically stable at neutral pH, and then release the hydrophobic active agent at a pH range indicative of food spoilage. By releasing the hydrophobic dye and/or antimicrobial agent, the nanoparticles can detect and/or inhibit food spoilage.