5464-60-8Relevant articles and documents
Synthesis and electrocatalytic properties of a dinuclear copper(II) complex for generating hydrogen from acetic acid or water
Fang, Ting,Li, Wei,Zhan, Shu-Zhong,Wei, Xiao-Lan
, p. 573 - 585 (2015)
The reaction of CuCl2s2H2O and a tetradentate amine phenol ligand affords a dinuclear Cu(II) complex, 1, a new molecular electrocatalyst, whose structure has been determined by X-ray crystallography. Electrochemical studies show that
Synthesis, characterization, and X-ray crystal structure of cobalt(III) complexes with a N2O2-donor Schiff base and ancillary ligands. Spectral, antibacterial activity, and electrochemical studies
Salehi, Mehdi,Amirnasr, Mehdi,Meghdadi, Soraia,Mereiter, Kurt,Bijanzadeh, Hamid R.,Khaleghian, Ali
, p. 90 - 97 (2014)
The synthesis and characterization of a series of cobalt(III) complexes of the general type trans-[Co(Me-salen)(L2)]X, are described. The H 2Me-salen = N,N′-bis(methylsalicylidene)-1,2-ethylenediimine) and the two ancillary ligands (
Syntheses, three types of hydrogen-bonded assembly structures, and magnetic properties of [FeIII(Him)2(hapen)]Y·solvent (Him = imidazole, hapen =N,N′-bis(2-hydroxyacetophenylidene)ethylenediamine, y = BPh4-, CF<
Koike, Masataka,Murakami, Keishiro,Fujinami, Takeshi,Nishi, Koshiro,Matsumoto, Naohide,Sunatsuki, Yukinari
, p. 185 - 192 (2013)
Five iron(III) complexes of [FeIII(Him)2(hapen)] Y·solvent with five different counter anions were synthesized, where Him = imidazole, H2hapen = N,N′-bis(2-hydroxyacetophenylidene) ethylenediamine, Y = BPh4
Diorgano-gallium and -indium complexes with salen ligands: Synthesis, characterization, crystal structure and C-C coupling reactions
Kushwah, Nisha P.,Pal, Manoj K.,Wadawale, Amey P.,Jain, Vimal K.
, p. 2375 - 2379 (2009)
The reactions of triorgano-gallium and -indium etherate with salen ligands in benzene afforded complexes of the type [R2MOC6H4CR′{double bond, long}NCH2-]2, (R/M/R′ = Me/Ga/H (1), Et/Ga/H (2), Me/In/H (3), Et/Ga/Me (4)) in nearly quantitative yields. These complexes have been characterized by elemental analysis, IR, UV-Vis, NMR (1H and 13C{1H}) and mass spectral data. The organogallium complexes showed photoluminescence in blue-green region. The complex, [(Me2Ga)2(O-(C6H4)CH{double bond, long}N-CH2-)2] on recrystallization from benzene-hexane and dichloromethane gave orthorhombic and monoclinic forms, respectively. Both the forms are dimeric with gallium atoms acquiring a distorted tetrahedral configuration defined by two methyl groups, phenolate oxygen and azomethene nitrogen. The complexes [(Me2Ga)2(O-(C6H4)CH{double bond, long}N-CH2-)2] and [(Me2In)2(O-(C6H4)CH{double bond, long}N-CH2-)2] have been employed as alkylating agent for C-C coupling reaction of 1-bromonaphthalene in presence of PdCl2(PPh3)2.
Novel nanohybrids of cobalt(III) Schiff base complexes and clay: Synthesis and structural determinations
Kianfar, Ali Hossein,Mahmood, Wan Ahmad Kamil,Dinari, Mohammad,Azarian, Mohammad Hossein,Khafri, Fatemeh Zare
, p. 422 - 428 (2014)
The [Co(Me2Salen)(PBu3)(OH2)]BF 4 and [Co(Me2Salen)(PPh3)(Solv)]BF4, complexes were synthesized and characterized by FT-IR, UV-Vis, 1H NMR spectroscopy and elemental a
Synthesis, crystal structure, chromatographic seperation, and thermogravimetric investigation of a ONNO type asymmetric Schiff base and its trinuclear complexes
Oez,Ergun,Yakut,Svoboda,Atakol,Kuebra Inal,Yilmaz,Atakol
, p. 571 - 582 (2014/08/18)
1,3-Propanediamine was put to react with 2-hydroxybenzaldehyde and 2-hydroxyacetophenone sequentially in aprotic medium. The crystalline product was examined by high performance liquid chromatography. The composition was 66% asymmetric Schiff base N(2-hydroxybenzylidene)-N'(2-hydroxyacetophenone)-1,3- propanediamine (SALLACH2) and 33% bis-N,N'(2-hydroxyacetophenylidene) -1,3-propanediamine (LACH2). As the crystals were uniform and of appropriate size, the molecular model of the material was revealed by X-ray diffraction. It was seen that two molecules of SALLACH2 and one molecule of LACH 2 formed the mixed crystals. The substance was separated to its components and the asymmetric Schiff base was purified with a silica column. The substance was characterized with elemental analysis, FT-IR, MS, 1HNMR, and 13C NMR. In addition, six tri-nuclear complex with the nuclear structure of NiII-NiII-NiII, NiII-CuII-NiII, NiII-Mn II-NiII were prepared from this Schiff base and stoichiometry was determined by elemental analysis, FT-IR and thermogravimetry. Finally, the molecular structures of two complexes were brought to light by XRD which highlights the asymmetry of the ligand more clearly.