5466-94-4

Basic information

• Product Name: 4-nitro-N-phenylbenzenecarboximidoyl chloride
• CAS NO: 5466-94-4
• Molecular Formula: C₁₃H₉ClN₂O₂
• Molecular Weight: 260.6758
• Mol File: 5466-94-4.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 405.1°C at 760 mmHg
• Flash Point: 198.8°C
• Density: 1.27g/cm³
• Vapor Pressure: 2.1E-06mmHg at 25°C
• Refractive Index: 1.608
• CAS DataBase Reference: 4-nitro-N-phenylbenzenecarboximidoyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 4-nitro-N-phenylbenzenecarboximidoyl chloride(5466-94-4)
• EPA Substance Registry System: 4-nitro-N-phenylbenzenecarboximidoyl chloride(5466-94-4)

Safety Data

• Hazardous Substances Data: 5466-94-4(Hazardous Substances Data)

Upstream product

• 3460-11-5 4-nitrobenzanilide 
• 122-04-3 4-nitro-benzoyl chloride 
• 62-23-7 4-nitro-benzoic acid 
• 62-53-3 aniline 

Downstream Products

• 1226-45-5 (4-(dimethylamino)phenyl)(4-nitrophenyl)methanone 
• 38921-51-6 4-nitro-N-phenyl-benzimidic acid phenyl ester 
• 19555-22-7 4-nitro-N,N'-diphenyl-benzamidine 
• 21010-44-6 N-(2-Chloro-ethyl)-4-nitro-N-phenyl-benzamide 
• 82040-42-4 2-(4-Nitro-phenyl)-1,7-diphenyl-1H-thiazolo[3,4-b][1,2,4]triazole-5-thione 
• 3460-11-5 4-nitrobenzanilide 
• 81617-48-3 N-(2-Acetylamino-5-methyl-phenyl)-4-nitro-N-phenyl-benzamide 
• 113934-53-5 N-phenyl-p-nitrobenzimidic ester of 3,5,7-trimethyltropolone 
• 106185-00-6 N-Methyl-N'-(4-nitro-N-phenylbenzimidoyl)thioharnstoff 
• 14213-27-5 1-phenyl-5-(4-nitrophenyl)-1H-tetrazole 
• 6333-15-9 4,4'-dinitrobenzanilide 
• 33490-01-6 4-nitro-N-(2-nitrophenyl)benzamide 

Relevant articles and documents

Novel Conjugated s-Tetrazine Derivatives Bearing a 4H-1,2,4-Triazole Scaffold: Synthesis and Luminescent Properties

A series of new symmetrical s-tetrazine derivatives, coupled via a 1,4-phenylene linkage with a 4H-1,2,4-triazole ring, were obtained. The combination of these two rings in an extensively coupled system has significant potential applications, mainly in op

α-Imino Iridium Carbenes from Imidoyl Sulfoxonium Ylides: Application in the One-Step Synthesis of Indoles

Imidoyl sulfoxonium ylides are presented for the first time as potential precursors to generate α-imino metal-carbene intermediates and applied in direct C-H functionalization reactions catalyzed by [Ir(cod)Cl]2 (4 mol %) to provide 2-substituted indoles (up to 70% yield) in just one step. This class of sulfur ylide is successfully obtained from imidoyl chloride and dimethylsulfoxonium methylide (23 new examples in 45-85% yield) or by imino group formation from the corresponding β-keto sulfoxonium ylides and anilines in the presence of TiCl4 as a Lewis acid (9 examples in 33-94% yield).

Solvent/oxidant-switchable synthesis of multisubstituted quinazolines and benzimidazoles via metal-free selective oxidative annulation of arylamidines

A fast and simple divergent synthesis of multisubstituted quinazolines and benzimidazoles was developed from readily available amidines, via iodine(III)-promoted oxidative C(sp3)-C(sp2) and C(sp 2)-N bond formation in nonpolar and polar solvents, respectively. Further selective synthesis of quinazolines in polar solvent was realized by TEMPO-catalyzed sp3C-H/sp2C-H direct coupling of the amidine with K2S2O8 as the oxidant. No metal, base, or other additives were needed.