5468-85-9

Basic information

• Product Name: N-phenyl-2-quinolinamine
• Synonyms: N-phenyl-2-quinolinamine;2-Anilinoquinoline
• CAS NO: 5468-85-9
• Molecular Formula: C₁₅H₁₂N₂
• Molecular Weight: 220.27
• Mol File: 5468-85-9.mol
• Article Data: 23

Chemical Properties

• Appearance: /
• Density: 1.15g/cm³
• Refractive Index: 1.571
• CAS DataBase Reference: N-phenyl-2-quinolinamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-phenyl-2-quinolinamine(5468-85-9)
• EPA Substance Registry System: N-phenyl-2-quinolinamine(5468-85-9)

Safety Data

• Hazardous Substances Data: 5468-85-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C19H21N3O3/c1-14-7-6-10-17(11-14)25-13-19(24)20-12-18(23)22-21-15(2)16-8-4-3-5-9-16/h3-11H,12-13H2,1-2H3,(H,20,24)(H,22,23)/b21-15+

Upstream product

• 612-62-4 2-Chloroquinoline 
• 1865-45-8 sodium anilide 
• 62-53-3 aniline 
• 32888-95-2 (4-chloro-quinolin-2-yl)-phenyl-amine 
• 144752-25-0 Phenyl-(2-vinyl-phenyl)-carbodiimide 
• 109586-44-9 trifluoromethanesulfonic acid quinolin-2-yl ester 
• 7647-01-0 hydrogenchloride 
• 64-19-7 acetic acid 
• 103-71-9 phenyl isocyanate 
• 138386-61-5 1-ethynyl-N-(triphenylphosphoranylidene)benzeneamine 
• 59-31-4 2-hydroxyquinoline 
• 3867-18-3 2-vinylaniline 
• 138386-53-5 C₂₆H₂₂NP 
• 15580-32-2 malonanilic acid 

Downstream Products

• 85291-53-8 2,4-Diphenyl-2,3-dihydro-1H-pyrimido<3,4-a>chinolin-1,3-dion 
• 85291-49-2 4-Benzyl-2-phenyl-2,3-dihydro-1H-pyrimido<3,4-a>chinolin-1,3-dion 
• 70611-37-9 2-Benzyl-1-oxo-4-phenyl-1H-pyrimido<1,2-a>chinolin-4-ium-3-olat 
• 243-38-9 6H-quinindoline 
• 114414-78-7 neocryptolepine 
• 85291-56-1 2-Phenyl-2,3-dihydro-1H-pyrimido<3,4-a>chinolin-1,3-dion 
• 85291-48-1 3-Benzyl-1-(2-chinolinyl)-4-hydroxy-chinolin-2(1H)-on 
• 85291-57-2 4,4,4a-Trichlor-2-phenyl-2,3,4,4a-tetrahydro-1H-pyrimido<3,4-a>chinolin-1,3-dion 
• 205-54-9 quinolino<1,2-a>benzimidazole 
• 1283073-99-3 2-(2,3-diphenyl-1H-indol-1-yl)quinoline 
• 1542248-04-3 1-acetyl-1-tert-butyl-3-phenyl-3-quinolin-2-yl-urea 

Relevant articles and documents

Cyano-Sacrificial (Arylthio)arylamination of Quinoline and Isoquinoline N-Oxides Using N-(2-(Arylthio)aryl)cyanamides

A copper(I)-catalyzed regioselective arylthio-arylamination of quinoline and isoquinoline N-oxides has been achieved at the expense of a cyano (CN) group from N-(2-(arylthio)aryl)cyanamides. This reductive amination proceeds in one pot at 80 °C in the absence of any additives. This is a unique demonstration of aryl cyanamides serving as arylaminating agents on quinoline/isoquinoline N-oxides with concurrent autoreduction of N-oxide.

Design of Benzimidazolyl Phosphines Bearing AlterableP,OorP,N-Coordination: Synthesis, Characterization, and Insights into Their Reactivity

A new series of hemilabile benzimidazolyl phosphines is reported. Entities in this ligand family can be easily assembled and prepared on a large scale via a simple one-pot procedure. X-ray crystallographic analyses show that the Pd metal center can coordinate in different fashions, where it relies on the size of the ?PR2group. With the same ligand scaffold, the ligand having a ?PCy2moiety displays better efficiency in expediting aromatic C-C bond-coupling reactions, while the ligand associated with a ?P-t-Bu2group, in contrast, promotes C-N bond-forming reactions.

A mild and metal-free synthesis of 2- And 1-alkyl/aryl/dialkyl-aminoquinolines and isoquinolines

A simple synthetic strategy has been developed for the synthesis of 2- and 1-alkyl/aryl/dialkylaminoquinolines and isoquinolines from the easily available quinoline and isoquinoline-N-oxides, different amines, triflic anhydride as activating agent and ace